Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone

Caracelli I.; Olivato P.R.; Traesel H.J.; Valen#231; a J.; Rodrigues D.N.S.; Tiekink E.R.T.

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Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone

机译：2-甲氧基-2-[[（4-甲氧基苯基）硫烷基] -1-苯基乙酮的晶体结构

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In the title β-thiocarbonyl compound, C16H16O3S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the methoxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H⋯O(carbonyl) interactions that lead to a supramolecular chain with a zigzag topology along the c axis. Chains pack with no specific intermolecular interactions between them.

机译：在标题β-硫代羰基化合物C16H16O3S中，相邻的甲氧基和羰基O原子为同上平面[OC-C-O扭转角为19.8（4）°]，并隔开2.582（3）Å。环之间的二面角为40.11°（16）°，甲氧基与与其相连的苯环共面[CC-OC扭转角为179.1°（3）°]。晶体堆积的最显着特征是次甲基和甲基CHOH（羰基）相互作用的形成，导致沿c轴呈锯齿形的超分子链。链条之间没有特定的分子间相互作用。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第9期|共页
作者
Caracelli I.; Olivato P.R.; Traesel H.J.; Valen#231; a J.; Rodrigues D.N.S.; Tiekink E.R.T.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTUREC-H...O INTERACTIONSBETA-THIOCARBONYLCONFORMATION;

机译：晶体结构C-H ... O相互作用[BETA]-硫羰基构象;

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1. Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone [J] . Caracelli I., Olivato P.R., Traesel H.J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

机译：2-甲氧基-2-[[（4-甲氧基苯基）硫烷基] -1-苯基乙酮的晶体结构
2. Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone [J] . Caracelli I., Olivato P.R., Traesel H.J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

机译：2-甲氧基-2-[[（4-甲氧基苯基）硫烷基] -1-苯基乙酮的晶体结构
3. Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone [J] . Caracelli I., Olivato P.R., Traesel H.J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

机译：2-甲氧基-2-[[（4-甲氧基苯基）硫烷基] -1-苯基乙酮的晶体结构
4. Fluorescence, computational enactments of dimethyl N,N'-(ethyne-1, 2-di-yl)Bis-(1,4-phenyl-ene carbon-yl)bis-(l-alaninate) crystals [C] . K. Senthil Kannan, P. Thamarikannan, V. Kalaipoonguzhali, International Conference on Physics and Chemistry of Materials in Novel Engineering Applications . 2020

机译：荧光，二甲基N，N' - （乙炔-1,2-二-Y1）双 - （1,4-苯基 - 烯烃碳-Y1）双（L-丙酸盐）晶体
5. Crystal structure of 2-methoxy-2-(4-methoxyphenyl)sulfanyl-1-phenylethanone [O] . Ignez Caracelli, Paulo R. Olivato, Henrique J. Traesel, 2015

机译：2-甲基氧基-2-（4-甲基氧基苯甲酰基）硫s基 -1-苯基乙酮的晶体结构
6. Crystal structure of {2-hydroxy-2-(3-methoxyphenyl)cyclohexylmethyl}dimethylammonium benzoate [O] . Sheshadri S. N., Nagendra P., Siddaraju B. P., 2015

机译：{2-羟基氧基-2-（3-甲基氧基苯基）环己基甲基}二甲基苯甲酸铵的晶体结构

Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone

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Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone