Crystal structure of (μ-N-allyl­thio­urea-κ2S:S)bis­[μ-bis­(di­phenyl­phosphanyl)methane-κ2P:P′]bis­[bromido­copper(I)] aceto­nitrile disolvate

Hemman M.; Pakawatchai C.; Boonmak J.; Youngme S.; Saithong S.

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Crystal structure of (μ-N-allylthiourea-κ2S:S)bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]bis[bromidocopper(I)] acetonitrile disolvate

机译：（μ-N-烯丙基硫脲-κ2S：S）双[μ-双（二苯基膦基）甲烷-κ2P：P']双[溴代铜（I）]乙腈的晶体结构

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The reaction of cuprous bromide with a mixture of 1,1-bis(diphenylphosphanyl)methane (dppm: C25H22P2) and N-allylthiourea (ATU: C4H8N2S) in acetonitrile yielded the title solvated dinuclear complex, [Cu2Br2(C4H8N2S)(C25H22P2)2]·2C2H3N or [Cu2Br2(ATU)(dppm)2]·2CH3CN. Both Cu+ ions adopt distorted tetrahedral geometries, being coordinated by one terminal Br atom, one μ2-S atom of the bridging ATU ligand and two P atoms of the bridging dppm ligands. Within the complex, intramolecular C—H⋯S, C—H⋯π, N—H⋯Br and π–π stacking interactions are observed. In the crystal, the components are linked by N—H⋯Br and C—H⋯N hydrogen bonds and weak π–π stacking interactions, generating chains propagating in the [100] direction.

机译：溴化亚铜与1,1-双（二苯基膦基）甲烷（dppm：C25H22P2）和N-烯丙基硫脲（ATU：C4H8N2S）在乙腈中的混合物反应生成标题为溶剂化的双核络合物[Cu2Br2（C4H8N2S）（C25H22P2）2 ]·2C2H3N或[Cu2Br2（ATU）（dppm）2]·2CH3CN。两种Cu +离子均采用扭曲的四面体几何形状，由一个末端Br原子，一个桥接ATU配体的一个μ2-S原子和两个桥接dppm配体的两个P原子配位。在复合物中，观察到分子内的CHS，CHHπ，NHBr和π-π堆积相互作用。在晶体中，这些成分通过N-H⋯Br和C-H⋯N氢键和弱的π-π堆积相互作用连接，从而生成沿[100]方向传播的链。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第9期|共4页
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Hemman M.; Pakawatchai C.; Boonmak J.; Youngme S.; Saithong S.;
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1. Crystal structure of (μ-N-allylthiourea-κ2S:S)bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]bis[bromidocopper(I)] acetonitrile disolvate [J] . Hemman M., Pakawatchai C., Boonmak J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

机译：（μ-N-烯丙基硫脲-κ2S：S）双[μ-双（二苯基膦基）甲烷-κ2P：P']双[溴代铜（I）]乙腈的晶体结构
2. Crystal structure of bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]-μ-chlorido-chlorido-1κCl-(1-phenylthiourea-2κS)disilver acetonitrile hemisolvate [J] . Nimthong-Rold#225, n A., Ratthiwal J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第6期

机译：双[μ-双（二苯基膦基）甲烷-κ2P：P']-μ-氯-氯-1κCl-（1-苯基硫脲-2κS）二乙腈半溶剂化物的晶体结构
3. Crystal structure of bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]-μ-chlorido-chlorido-1κCl-(1-phenylthiourea-2κS)disilver acetonitrile hemisolvate [J] . Nimthong-Rold#225, n A., Ratthiwal J., Acta Crystallographica Section E: Crystallographic Communications . 2015,第6期

机译：双[μ-双（二苯基膦基）甲烷-κ2P：P']-μ-氯-氯-1κCl-（1-苯基硫脲-2κS）二乙腈半溶剂化物的晶体结构
4. Crystal structure of (μ-N-allylthiourea-κ2S:S)bisμ-bis(diphenylphosphanyl)methane-κ2P:P′bisbromidocopper(I) acetonitrile disolvate [O] . Mareeya Hemman, Chaveng Pakawatchai, Jaursup Boonmak, 2015

机译：（μ-N-烯丙基硫脲-κ2的晶体结构S：S）bis μ-bis（二苯基苯基膦基）甲烷-κ2P：P双溴omi铜（I）乙腈二溶剂化物
5. Bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′](μ-1-ethylthiourea-κ2S:S)bis[iodidocopper(I)] acetonitrile sesquisolvate [O] . Ruthairat Nimthong, Yupa Wattanakanjana, Chaveng Pakawatchai 2013

机译：双[＆＃956; - 双（二苯基磷烷基）甲烷 - ＆＃954; 2p：p＆＃8242;]（＆＃956; -1-乙基硫脲 - ＆＃954; 2s：s）双[碘化铜（I）]乙腈sesquisolvate

Crystal structure of (μ-N-allyl­thio­urea-κ2S:S)bis­[μ-bis­(di­phenyl­phosphanyl)methane-κ2P:P′]bis­[bromido­copper(I)] aceto­nitrile disolvate

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Crystal structure of (μ-N-allylthiourea-κ2S:S)bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]bis[bromidocopper(I)] acetonitrile disolvate