Crystal structure of di­aqua­bis­(4-cyano­pyridine-κN)bis­(thio­cyanato-κN)iron(II) 4-cyano­pyridine disolvate

Jochim A.; Jess I.; N#228; ther C.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate

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Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate

机译：二氰基（4-氰基吡啶-κN）双（硫氰基-κN）铁（II）4-氰基吡啶二溶剂化物的晶体结构

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The asymmetric unit of the title compound, [Fe(NCS)2(C6H4N2)2(H2O)2]·2C6H4N2, comprises one FeII cation occupying an inversion centre as well as one thiocyanate anion, one water molecule and two 4-cyanopyridine molecules in general positions. The iron cations are coordinated by two N-bonded thiocyanate anions, two (pyridine)N-bonded 4-cyanopyridine ligands and two water molecules into discrete complexes. The resulting coordination polyhedron can be described as a slightly distorted octahedron. The discrete complexes are connected through centrosymmetric pairs of (pyridine)C—H⋯N(cyano) hydrogen bonds into chains that are further linked into a three-dimensional network through intermolecular O—H⋯N hydrogen bonds involving the 4-cyanopyridine solvent molecules.

机译：标题化合物[Fe（NCS）2（C6H4N2）2（H2O）2]·2C6H4N2的不对称单元包含一个占据反转中心的FeII阳离子以及一个硫氰酸根阴离子，一个水分子和两个4-氰基吡啶分子一般职位。铁阳离子由两个N键合的硫氰酸根阴离子，两个（吡啶）N键合的4-氰基吡啶配体和两个水分子配位成离散的络合物。所得的配位多面体可以描述为稍微变形的八面体。离散的配合物通过（吡啶）C-H⋯N（氰基）氢键的中心对称对连接成链，这些链通过涉及4-氰基吡啶溶剂分子的分子间OH-H⋯N氢键进一步连接成三维网络。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第4期|共4页
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Jochim A.; Jess I.; N#228; ther C.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTUREHYDROGEN BONDING4-CYANOPYRIDINEIRONTHIOCYANATE;

机译：晶体结构氢键4-氰基吡啶二异氰酸酯;

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1. Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate [J] . Jochim A., Jess I., N#228, Acta Crystallographica Section E: Crystallographic Communications . 2017,第4期

机译：二氰基（4-氰基吡啶-κN）双（硫氰基-κN）铁（II）4-氰基吡啶二溶剂化物的晶体结构
2. Crystal structure of bis[4-(dimethylamino)pyridine-κN1]bis(methanol-κO)bis(thiocyanato-κN)manganese(II) [J] . Suckert S., Jess I., N#228, Acta Crystallographica Section E: Crystallographic Communications . 2015,第5期

机译：双[4-（二甲基氨基）吡啶-κN1]双（甲醇-κO）双（硫氰酸根-κN）锰的晶体结构（II）
3. Crystal structure of bis[4-(dimethylamino)pyridine-κN1]bis(methanol-κO)bis(thiocyanato-κN)manganese(II) [J] . Suckert S., Jess I., N#228, Acta Crystallographica Section E: Crystallographic Communications . 2015,第5期

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4. The X-ray crystallographic structure of phytanoyl-coenzyme A hydroxylase, an iron(II) 2-oxoglutarate dependent dioxygenase involved in Refsum's disease. [D] . Odell, Lindsay Thomas. 2004

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5. Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate [O] . Aleksej Jochim, Inke Jess, Christian Näther 2017

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7. Moessbauer Study of Some Iron (III) Complexes with Urea-Type Ligands and Crystal Structure of Hexakisdimethylurea Iron (III) Perchlorate [R] . Calogero, S., Galeazzi, G., Russo, U., 1980

机译：moessbauer研究一些具有尿素型配体的铁（III）配合物和Hexakisdimethylurea铁（III）高氯酸盐的晶体结构

Crystal structure of di­aqua­bis­(4-cyano­pyridine-κN)bis­(thio­cyanato-κN)iron(II) 4-cyano­pyridine disolvate

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Crystal structure of diaquabis(4-cyanopyridine-κN)bis(thiocyanato-κN)iron(II) 4-cyanopyridine disolvate