Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

Ouis S.; Rouag D.A.; Bendjeddou L.; Bailly C.

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Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

机译：含氢化物和磷化物配体桥接的金属-金属键的同核铂络合物的晶体结构

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In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H(C18H15P)2]·C4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]·(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H⋯·O and C—H⋯π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each PtII atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio.

机译：在标题化合物中，μ-二苯基膦基-μ-氢-双[溴（三苯基膦-κP）铂（II）]二乙醚单溶剂化物，[Pt2Br2（C12H10P）H（C18H15P）2]·C4H10O或[Pt2（μ-H））（μ-PPh2）Br2（PPh3）2]·（C2H5）2O上，PtII原子以扭曲的方平面排列配位，一个氢和一个磷配体桥连在反式位置。在晶格中，存在CH-O和CH-π相互作用。该络合物的总数为32个电子，每个PtII原子16个电子。 Br原子之一在两个位置上以0.92：0.08的比率无序排列。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2018年第7期|共4页
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Ouis S.; Rouag D.A.; Bendjeddou L.; Bailly C.;
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中图分类晶体学;
关键词
PLATINUM(II) COMPLEXHYDRIDO BRIDGEPHOSPHIDE LIGANDCRYSTAL STRUCTURE;

机译：铂（II）络合桥磷化锂晶体结构;

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Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

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