Crystal structure and luminescent properties of [1-(biphenyl-4-yl)-1H-imidazole-κN3]di­chloridozinc

Liu X.-X.; Wang Y.

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Crystal structure and luminescent properties of [1-(biphenyl-4-yl)-1H-imidazole-κN3]dichloridozinc

机译：[1-（联苯-4-基）-1H-咪唑-κN3]二氯咪唑的晶体结构和发光性能

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The mononuclear title compound, [ZnCl2(C15H12N2)2], was synthesized by reaction of zinc chloride and 1-(biphenyl-4-yl)-1H-imidazole (bpi) under hydrothermal conditions. The ZnII atom is tetrahedrally coordinated by the free imidazole N atoms of two bpi ligands and by two Cl atoms. The bpi ligands are not planar, with dihedral angles of 37.52 (14) and 42.45 (14)° between the phenyl rings and 37.13 (14) and 40.05 (14)° between the phenyl rings and the attached imidazole rings, respectively. Mutual π–π interactions, with a centroid-to-centroid distance of 3.751 (2) Å between the phenyl and imidazole rings of neighbouring ligands, are present, leading to dimers that are arranged in rows parallel to [-211].

机译：在水热条件下，氯化锌与1-（联苯基-4-基）-1H-咪唑（bpi）反应合成了单核标题化合物[ZnCl2（C15H12N2）2]。 ZnII原子由两个bpi配体的游离咪唑N原子和两个Cl原子四面体配位。 bpi配体不是平面的，苯环之间的二面角分别为37.52（14）和42.45（14）°，苯环和连接的咪唑环之间的二面角分别为37.13（14）和40.05（14）°。存在相互的π-π相互作用，相邻配体的苯基和咪唑环之间的质心到质心的距离为3.751（2）Å，导致二聚体平行于[-211]行排列。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第3期|共3页
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Liu X.-X.; Wang Y.;
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Crystal structure and luminescent properties of [1-(biphenyl-4-yl)-1H-imidazole-κN3]di­chloridozinc

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Crystal structure and luminescent properties of [1-(biphenyl-4-yl)-1H-imidazole-κN3]dichloridozinc