Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ2O:O′] dihydrate]

Liu Y.; Xu L.-Y.; Zhang H.-T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2O:O′] dihydrate]

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Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2O:O′] dihydrate]

机译：链状聚[[[[aquabis（1H-咪唑-κN3）铜（II）]]-μ-3-（{4-[（（2-羧乙基乙基）氨基甲酰基]苯基}甲酰胺基）丙烷-κ2O：O']的晶体结构二水合物]

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In the title polymeric complex, {[Cu(C14H14N2O6)(C3H4N2)2(H2O)]·2H2O}n, the CuII cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]formamido)propanoate dianions (L2−) in an approximately square-pyramidal geometry. The coordinating water molecule is located on a twofold rotation axis while the L2− anion sits about an inversion center. The L2− anions bridge the CuII cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π interaction link the polymeric chains and the solvent water molecules into a three-dimensional supramolecular architecture.

机译：在标题聚合物络合物{[Cu（C14H14N2O6）（C3H4N2）2（H2O）]·2H2O} n中，位于两倍旋转轴上的CuII阳离子由一个水分子和两个咪唑分子以及两个与对称相关的3-（[[4-[（2-羧基-乙基乙基）氨基甲酰基]苯基]甲酰胺基）丙酸二价阴离子（L2-）呈近似金字塔形。配位水分子位于两倍旋转轴上，而L2-阴离子位于反转中心附近。 L2-阴离子桥接CuII阳离子，形成沿[101]方向传播的聚合物链。在晶体中，OH-O，NH-O氢键和弱CH-π相互作用将聚合物链和溶剂水分子连接成三维超分子结构。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第5期|共页
作者
Liu Y.; Xu L.-Y.; Zhang H.-T.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTURECUII COORDINATION POLYMERHYDROGEN BONDINGC-H...PI INTERACTIONS;

机译：晶体结构配位聚合物氢键C-H ... [PI]相互作用;

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1. Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2O:O′] dihydrate] [J] . Liu Y., Xu L.-Y., Zhang H.-T. Acta Crystallographica Section E: Crystallographic Communications . 2015,第5期

机译：链状聚[[[[aquabis（1H-咪唑-κN3）铜（II）]]-μ-3-（{4-[（（2-羧乙基乙基）氨基甲酰基]苯基}甲酰胺基）丙烷-κ2O：O']的晶体结构二水合物]
2. Crystal structure of catena-poly[[[dichloridocopper(II)]-{μ-tert-butyl N-methyl-N-[4-(6-{[4-(pyridin-2-yl-κN)-1H-1,2,3-triazol-1-yl-κN3]methyl}-1,3-benzothiazol-2-yl)phenyl]carbamato}] acetonitrile monosolvate] [J] . Pocinho A., Duhayon C., Gras E., Acta Crystallographica Section E: Crystallographic Communications . 2018,第2期

机译：链状聚[[[[dichloridocopper（II）]]-{μ-叔丁基N-甲基-N- [4-（6-{[4-（吡啶-2-基-κN）-1H-1 ，2,3-三唑-1-基-κN3]甲基} -1,3-苯并噻唑-2-基）苯基]氨基甲酸酯}]乙腈单溶剂合物]
3. Crystal structure of catena-poly[[bis(acetato-κO)copper(II)]-bis[μ-4-(1H-imidazol-1-yl)phenol]-κ2N3:O;κ2O:N3] [J] . Poyraz M., Sar#305, M. Acta Crystallographica Section E: Crystallographic Communications . 2017,第2期

机译：链状聚[[双（乙酰基-κO）铜（II）]-双[μ-4-（1H-咪唑-1-基）苯酚]-κ2N3：O;κ2O：N3]的晶体结构
4. Crystal structure of catena-polyaquabis(1H-imidazole-κN3)copper(II)-μ-3-({4-(2-carboxylatoethyl)carbamoylphenyl}formamido)propanoato-κ2O:O′ dihydrate [O] . Yan Liu, Liu-Yang Xu, Hong-Tao Zhang 2015

机译：阳离子多聚水双（1H-咪唑-κN3）铜（II）-μ-3-（{4-（2-羧基乙炔基）氨基甲酰基苯基}甲酰胺基）丙酸酯-κ2O：O二水合物
5. Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2O:O′] dihydrate] [O] . Yan Liu, Liu-Yang Xu, Hong-Tao Zhang 2015

机译：catena-poly [[[aquabis（1H-imidazole-κN3）copper（II）] - μ-3 - （{4 - [（2-羧基乙酰基）氨基甲酰基]苯基}甲酰胺基）丙酸根-κ2O：O']的晶体结构二水]

Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ2O:O′] dihydrate]

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Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN3)copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2O:O′] dihydrate]