Crystal structure of catena-poly[N,N,N′,N′-tetra-methyl-guanidinium [(chlorido-cadmate)-di-μ-chlorido]]

Ndiaye M.; Samb A.; Diop L.; Maris T.

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Crystal structure of catena-poly[N,N,N′,N′-tetra-methyl-guanidinium [(chlorido-cadmate)-di-μ-chlorido]]

机译：链状聚[N，N，N'，N'-四甲基胍盐[[氯代-镉酸酯-二-μ-氯代]]的晶体结构

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In the structure of the title salt, {(C5H14N3)[CdCl3]}n, the CdII atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd—Cl distances in the range 2.4829?(4)–2.6402?(4)??. The bipyramids are condensed into a polyanionic zigzag chain extending parallel to [101]. The tetra-methyl-guanidinium cations are situated between the polyanionic chains and are linked to them through N—H?Cl hydrogen bonds, forming a layered network parallel to (010).

机译：在标题盐{（C5H14N3）[CdCl3]} n的结构中，复合阴离子的CdII原子由一个末端和四个桥接的Cl原子五配位。相应的配位多面体是扭曲的三角双锥，其Cd-Cl距离在2.4829？（4）–2.6402？（4）??范围内。双锥体缩合成平行于[101]延伸的聚阴离子之字形链。四甲基胍盐阳离子位于聚阴离子链之间，并通过NHCl Cl氢键与它们连接，形成平行于（010）的层状网络。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第1期|共3页
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Ndiaye M.; Samb A.; Diop L.; Maris T.;
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中图分类晶体学;
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Crystal structure of catena-poly[N,N,N′,N′-tetra-methyl-guanidinium [(chlorido-cadmate)-di-μ-chlorido]]

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