Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methyl­idene]isonicotino­hydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethyl­idene]hydrazinecarbo­thio­amide

Saranya S.; Haribabu J.; Bhuvanesh N.S.P.; Karvembu R.; Gayathri D.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methylidene]isonicotinohydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethylidene]hydrazinecarbothioamide

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Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methylidene]isonicotinohydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethylidene]hydrazinecarbothioamide

机译：Schiff碱衍生物（E）-N'-[（（1H-吲哚-3-基）亚甲基]异烟肼肼乙醇单溶剂化物和（E）-N-甲基-2- [1-（2-氧代-2H- 3-基铬亚乙基]肼甲硫代酰胺

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The crystal structures of two title Schiff base derivatives, C15H12N4O·C2H6O (1·EtOH) and C13H13N3O2S (2), were determined at 110 and 100 K, respectively. In the crystal of compound 1·EtOH, the (E)-N′-[(1H-indol-3-yl)methylidene]isonicotinohydrazide and ethanol molecules are linked by O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds, forming a tape structure running along the b-axis direction. The tapes are weakly linked via a C—H⋯N interaction. In the crystal of compound 2, (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethylidene]hydrazinecarbothioamide molecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming a helical chain along the b-axis direction. The chains are further linked into a layer expanding parallel to (102) through C—H⋯S interactions.

机译：确定了两种标题席夫碱衍生物C15H12N4O·C2H6O（1·EtOH）和C13H13N3O2S（2）的晶体结构，分别为110 K和100K。在化合物1·EtOH的晶体中，（E）-N'-[（1H-吲哚-3-基）亚甲基]异烟酰肼与乙醇分子通过OH-O，NH-O和N-连接。 H⋯N氢键形成沿b轴方向延伸的带状结构。这些磁带通过C–H⋯N相互作用弱连接。在化合物2的晶体中，（E）-N-甲基-2- [1-（2-（氧代-2H-铬-3-基）亚乙基]肼]碳硫羰酰胺分子通过NH-O和CH-连接。 O氢键沿b轴方向形成螺旋链。链进一步通过CHS相互作用与平行于（102）扩展的层连接。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第4期|共4页
作者
Saranya S.; Haribabu J.; Bhuvanesh N.S.P.; Karvembu R.; Gayathri D.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTURESCHIFF BASE DERIVATIVESISONICOTINOHYDRAZIDEHYDRAZINECARBOTHIOAMIDE;

机译：晶体结构碱基衍生物磺酰氨基肼基肼基碳酰胺;

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1. Crystal structures of two hydrazinecarbothioamide derivatives: (E)-N-ethyl-2-[(4-oxo-4H-chromen-3-yl)methylidene]hydrazinecarbothioamide hemihydrate and (E)-2-[(4-chloro-2H-chromen-3-yl)methylidene]-N-phenylhydrazinecarbothioamide [J] . Gangadharan R., Haribabu J., Karvembu R., Acta Crystallographica Section E: Crystallographic Communications . 2015,第3期

机译：两种肼基甲硫基酰胺衍生物的晶体结构：（E）-N-乙基-2-[（4-氧代-4H-铬-3-基）亚甲基]肼基甲硫基酰胺半水合物和（E）-2-[（4-氯-2H- -3-（1-（3-苯基）亚甲基铬] -N-苯基肼基碳硫酰胺
2. {2-[1-(2-Methoxy-6-oxidophenyl-κO6)ethylidene]-N-methylhydrazinecarbothioamidato-κ2N2,S}(triphenylphosphane-κP)palladium(II) ethanol monosolvate [J] . Anderson B.J., Jasinski J.P., Keeler A.M., Acta Crystallographica Section E: Crystallographic Communications . 2013,第10期

机译：{2- [1-（2-甲氧基-6-氧化苯基-κO6）亚乙基] -N-甲基肼甲硫代酰胺基-κ2N2，S}（三苯基膦-κP）钯（II）乙醇单溶剂化物
3. Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate [J] . Aravindakshan A.A., Kurup M.R.P., Seena V., Acta Crystallographica Section E: Crystallographic Communications . 2014,第8期

机译：二氯基{（2E）-2- [苯基（吡啶-2-基）亚甲基]肼甲硫代酰胺}镉（II）甲醇单溶剂化物
4. Crystal Structures of Schiff Base Derivatives of 1-(3,4,5-Trimethoxybenzylidene)thiosemicarbazide and (E)-N'-(3-nitrobenzylidene)isonicotinohydrazide [C] . C. S. Dileep, L. Mallesh, M. A. Sridhar DAE Solid State Physics Symposium . 2014

机译：1-（3,4,4,4,5-三甲氧基苄基）硫代丙嗪和（e）-N' - （3-硝基苄基）异硝基肼的晶体结构
5. Crystal structures of the Schiff base derivatives (E)-N′-(1H-indol-3-yl)methylideneisonicotinohydrazide ethanol monosolvate and (E)-N-methyl-2-1-(2-oxo-2H-chromen-3-yl)ethylidenehydrazinecarbothioamide [O] . Sivaraj Saranya, Jebiti Haribabu, Nattamai S. P. Bhuvanesh, 2017

机译：席夫碱衍生物（E）-N-（（1H-吲哚-3-基）亚甲基异烟酰肼乙醇单溶剂化物和（E）-N-甲基-2- 1-（2-氧代-2H- -3-（3-（1-甲基）亚乙基铬肼碳硫代酰胺
6. Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methylidene]isonicotinohydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethylidene]hydrazinecarbothioamide [O] . Sivaraj Saranya, Jebiti Haribabu, Nattamai S. P. Bhuvanesh, 2017

机译：席夫碱衍生物（E）-N' - [（1H-吲哚-3-基）亚甲基]异烟酰肼乙醇单溶剂化物和（E）-N-甲基-2- [1-（2-氧代-2H-）的晶体结构色烯-3-基）亚乙基]肼硫代甲酰胺

Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methyl­idene]isonicotino­hydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethyl­idene]hydrazinecarbo­thio­amide

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Crystal structures of the Schiff base derivatives (E)-N′-[(1H-indol-3-yl)methylidene]isonicotinohydrazide ethanol monosolvate and (E)-N-methyl-2-[1-(2-oxo-2H-chromen-3-yl)ethylidene]hydrazinecarbothioamide