Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ2P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]

Khongsichan L.; Nimthong-Rold#225; n A.; Pakawatchai C.; Wongnawa S.

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Crystal structure of bis[μ-1,2-bis(diphenylphosphanyl)ethane-κ2P:P′]bis[(N,N′-diethylthiourea-κS)iodidocopper(I)]

机译：双[μ-1,2-双（二苯基膦基）乙烷-κ2P：P']双[（N，N'-二乙基硫脲-κS）碘多铜（I）]的晶体结构

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The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre. The CuI atom displays a distorted tetrahedral coordination geometry defined by one S atom of an N,N′-diethylthiourea ligand, two P atoms derived from two bridging 1,2-bis(diphenylphosphanyl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related CuI ions, forming a 10-membered Cu2P4C4 ring. An intramolecular N—H⋯I hydrogen bond is noted. In the crystal, N—H⋯I hydrogen bonds link complex molecules into layers parallel to (-101).

机译：双核标题复合物[Cu2I2（C26H24P2）2（C5H12N2S）2]围绕一个反转中心。 CuI原子显示出扭曲的四面体配位几何结构，该构型由N，N'-二乙基硫脲配体的一个S原子，两个桥联的1,2-双（二苯基膦基）乙烷（dppe）配体衍生的两个P原子和一个碘离子定义。 dppe配体桥接两个对称相关的CuI离子，形成一个10元的Cu2P4C4环。注意到分子内的NH-1氢键。在晶体中，NH 4氢键将复合分子连接到与（-101）平行的层中。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第9期|共页
作者
Khongsichan L.; Nimthong-Rold#225; n A.; Pakawatchai C.; Wongnawa S.;
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中图分类晶体学;
关键词
CRYSTAL STRUCTURECOPPER(I) COMPLEXN,N'-DIETHYLTHIOUREAN-H...I HYDROGEN BONDING;

机译：晶体结构铜（I）络合物;N'-二乙硫基-H ... I氢键;

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专利

1. Crystal structure of bis[μ-1,2-bis(diphenylphosphanyl)ethane-κ2P:P′]bis[(N,N′-diethylthiourea-κS)iodidocopper(I)] [J] . Khongsichan L., Nimthong-Rold#225, n A., Acta Crystallographica Section E: Crystallographic Communications . 2015,第9期

机译：双[μ-1,2-双（二苯基膦基）乙烷-κ2P：P']双[（N，N'-二乙基硫脲-κS）碘多铜（I）]的晶体结构
2. Crystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]di-μ3-bromido-trisilver(I) bromide–N,N′-phenylthiourea (1/1) [J] . Nimthong-Rold#225, n A., Wattanakanjana Y., Acta Crystallographica Section E: Crystallographic Communications . 2015,第4期

机译：三[μ2-双（二苯基膦基）甲烷-κ2P：P']二-μ3-溴-三溴化银（I）-N，N'-苯硫脲的晶体结构（1/1）
3. Crystal structure of [1,3-bis(diphenylphosphanyl)propane-κ2P,P′](N,N′-dimethylthiourea-κS)(thiocyanato-κN)copper(I) [J] . Wattanakanjana Y., Nimthong-Rold#225, n A., Acta Crystallographica Section E: Crystallographic Communications . 2015,第3期

机译：[1,3-双（二苯基膦基）丙烷-κ2P，P']（N，N'-二甲基硫脲-κS）（硫氰酸根-κN）铜的晶体结构（I）
4. Crystal structure of bisμ-12-bis(diphenylphosphanyl)ethane-κ2P:P′bis(NN′-diethylthiourea-κS)iodidocopper(I) [O] . Ladawan Khongsichan, Arunpatcha Nimthong-Roldán, Chaveng Pakawatchai, 2015

机译：双 μ-12-双（二苯基膦基）乙烷-κ2的晶体结构P：P bis （NN-二乙基硫基脲-κS）碘铜（I）
5. μ-1,2-Bis(diethylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diethylphosphino)ethane-κ2P,P′]trichloridonitrosyltungsten(II)} [O] . Heinz Berke, Helmut W. Schmalle, Olivier Blacque, 2008

机译：μ-1,2-双（二乙基膦基）乙烷-κ2P：P'-双{[1,2-双（二乙基膦基）乙烷-κ2P，P']三氯亚硝基钨（II）}

Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ2P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]

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Crystal structure of bis[μ-1,2-bis(diphenylphosphanyl)ethane-κ2P:P′]bis[(N,N′-diethylthiourea-κS)iodidocopper(I)]