Supra-molecular inter-actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro-thio-phene-2-carb-oxy-lic acid

Prajina O.; Thomas Muthiah P.; Geiger D.K.

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Supra-molecular inter-actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro-thio-phene-2-carb-oxy-lic acid

机译：4,4'-联吡啶和3-氯-硫代-吩-2-碳-氧-酸的1：2共晶体中的超分子相互作用

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The asymmetric unit of the title compound, 2C5H3ClO2S·C10H8N2, is comprised of a mol-ecule of 3-chloro-thio-phene-2-carb-oxy-lic acid (3TPC) and half of a mol-ecule of 4,4′-bi-pyridine (BPY). A distinctive O—H?N-based synthon is present. Cl?Cl and π–π stacking inter-actions further stabilize the crystal structure, forming a two-dimensional network parallel to the bc plane.

机译：标题化合物2C5H3ClO2S·C10H8N2的不对称单元由3-氯-硫代-吩-2-碳-氧-酸（3TPC）摩尔分子和4,4的摩尔分子一半组成′-联吡啶（BPY）。存在基于OH-N的独特合成子。 Cl？Cl和π–π堆积相互作用进一步稳定了晶体结构，形成了平行于bc平面的二维网络。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第10期|共4页
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Prajina O.; Thomas Muthiah P.; Geiger D.K.;
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中图分类晶体学;
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1. Supra-molecular inter-actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro-thio-phene-2-carb-oxy-lic acid [J] . Prajina O., Thomas Muthiah P., Geiger D.K. Acta Crystallographica Section E: Crystallographic Communications . 2016,第10期

机译：4,4'-联吡啶和3-氯-硫代-吩-2-碳-氧-酸的1：2共晶体中的超分子相互作用
2. Synthesis and structural characterization of organic co-crystals 4,4′-bipyridine-bis(N-phenylanthranilic acid) and 4,4′-bipyridinium bis(3-carboxypyridine-2-carboxylate) [J] . Kumaresan S., Seethalakshmi P.G., Kumaradhas P., Journal of Molecular Structure . 2013,第Null期

机译：有机共晶体4,4'-联吡啶-双（N-苯基邻氨基苯甲酸）和4,4'-联吡啶双（3-羧基吡啶-2-羧酸盐）的合成和结构表征
3. Classical and Weak Hydrogen Bonding Interactions between 4,4 '-Bipyridine and Organic Acids: From Co-Crystal to Organic Complex [J] . Nichol GS, Clegg W Crystal growth & design . 2009,第4期

机译：4,4'-联吡啶和有机酸之间的经典和弱氢键相互作用：从共晶体到有机配合物
4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(lll) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He International Conference on Advanced Engineering Materials and Technology . 2013

机译：两种新三维Ce（LLL）配位聚合物的合成，结构和性质用2,2'-硼烷-4,4'-二羧酸
5. Metal coordination polymers and organic co-crystals of polybenzoic acids and bipyridines. [D] . Lo, Man Fung. 2000

机译：金属配位聚合物和聚苯甲酸和联吡啶的有机共晶体。
6. (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)hydroxidocopper(II) monohydrate [O] . Li Yao, Wen-Juan Li 2016

机译：（Benzoato-κO）（苯甲酸-κO）（4,4'-二甲基-2,2'-联吡啶-κ2N，N'）一水合铜（II）
7. Crystal structures of three co-crystals of 4,4′-bipyridyl with 4-alkoxybenzoic acids: 4-ethoxybenzoic acid–4,4′-bipyridyl (2/1), 4-n-propoxybenzoic acid–4,4′-bipyridyl (2/1) and 4-n-butoxybenzoic acid–4,4′-bipyridyl (2/1) [O] . Yohei Tabuchi, Kazuma Gotoh, Hiroyuki Ishida 2015

机译：3,4'-联吡啶与4-烷氧基苯甲酸的三种共晶体的晶体结构：4-乙氧基苯甲酸-4,4'-联吡啶（2/1），4-正丙氧基苯甲酸-4,4'-联吡啶（2/1）和4-正丁氧基苯甲酸-4,4'-联吡啶（2/1）

Supra-molecular inter-actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro-thio-phene-2-carb-oxy-lic acid

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