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Inhibition of Phenylamide Hydrolysis by Bacillus sphaericus with Methylcarbamate and Organophosphorus Insecticides

机译:氨基甲酸甲酯和有机磷杀虫剂对球形芽孢杆菌的苯酰胺水解抑制作用

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The degradation of the phenylamide herbicides monolinuron, linuron, and solan by cultures of Bacillus sphaericus ATCC 12123 was inhibited by the methylcarbamate insecticides metmercapturon, aldicarb, propoxur, and carbaryl and by the organophosphorus insecticides fenthion and parathion. The extent of inhibition was largest with metmercapturon and smallest with parathion. Inhibition of hydrolysis of the two phenylurea herbicides was greater than of the acylanilide compound. Tests with crude enzyme preparations of aryl acylamidase derived from B. sphaericus showed that the inhibition of the hydrolysis of linuron with methylcarbamates is a competitive one. The insecticides tested did not induce the enzyme, nor could they serve as its substrate.
机译:球形芽孢杆菌ATCC 12123的培养对苯酰胺类除草剂单亚麻嘧啶,亚麻嘧啶和茄碱的降解受到甲基氨基甲酸酯杀虫剂灭草灵,涕灭威,丙草胺和西维因以及有机磷杀虫剂对硫磷和对硫磷的抑制。抑制作用的程度以氨甲蝶呤最大,对硫磷最小。两种苯基脲除草剂的水解抑制作用大于酰基丙酰胺化合物。用衍生自球形芽孢杆菌的芳基酰基酰胺酶的粗制酶制剂进行的试验表明,用氨基甲酸甲酯抑制亚麻嘧啶的水解是一种竞争性方法。测试的杀虫剂既不诱导酶,也不能作为酶的底物。

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