RBAP, a Rhodamine B-Based Derivative: Synthesis, Crystal Structure Analysis, Molecular Simulation, and Its Application as a Selective Fluorescent Chemical Sensor for Sn2+

Baojing Zhou; Xiaofeng Bao; Xiaowei Cao; Xuemei Nie; Yanyan Jin

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RBAP, a Rhodamine B-Based Derivative: Synthesis, Crystal Structure Analysis, Molecular Simulation, and Its Application as a Selective Fluorescent Chemical Sensor for Sn2+

机译：RBAP，基于罗丹明B的衍生物：合成，晶体结构分析，分子模拟及其在Sn 2 + 的选择性荧光化学传感器中的应用

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A new fluorescent chemosensor based on a Rhodamine B and a benzyl 3-aminopropanoate conjugate (RBAP) was designed, synthesized, and structurally characterized. Its single crystal structure was obtained and analyzed by X-ray analysis. In a MeOH/H₂O (2:3, v/v, pH 5.95) solution RBAP exhibits a high selectivity and excellent sensitivity for Sn2+ ions in the presence of many other metal cations. The binding analysis using the Job’s plot suggested the RBAP formed a 1:1 complex with Sn2+.

机译：基于罗丹明B和3-氨基丙酸苄酯共轭物（RBAP）的新型荧光化学传感器的设计，合成和结构表征。获得其单晶结构并通过X射线分析进行分析。在MeOH / H _{2 O（2：3，v / v，pH 5.95）溶液中，RBAP在存在下对Sn 2 + 离子具有高选择性和极好的敏感性许多其他金属阳离子。使用乔布图进行的结合分析表明，RBAP与Sn 2 + 形成了1：1的络合物。}

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《Molecules》 |2014年第6期|共15页
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Baojing Zhou; Xiaofeng Bao; Xiaowei Cao; Xuemei Nie; Yanyan Jin;
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1. RBAP, a Rhodamine B-Based Derivative: Synthesis, Crystal Structure Analysis, Molecular Simulation, and Its Application as a Selective Fluorescent Chemical Sensor for Sn~(2+) [J] . Xiaofeng Bao, Xiaowei Cao, Xuemei Nie Molecules . 2014,第6期

机译：RBAP，基于罗丹明B的衍生物：合成，晶体结构分析，分子模拟及其在Sn〜（2+）中作为选择性荧光化学传感器的应用
2. Design and synthesis of a new rhodamine B-based fluorescent probe for selective detection of glutathione and its application for live cell imaging [J] . Xiaolei Wu, Hai Shu, Baojing Zhou, Sensors and Actuators . 2016,第deca期

机译：新型基于若丹明B的谷胱甘肽选择性检测荧光探针的设计与合成及其在活细胞成像中的应用
3. A novel rhodamine B-based "off-on" fluorescent sensor for selective recognition of copper (II) ions [J] . Jiao Yang, Zhou Lu, He Haiyang, Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2018,第期

机译：基于罗丹明B的“脱机”荧光传感器，用于选择性识别铜（II）离子
4. Synthesis and Study of Fluorescent Probe Molecules Based on Rhodamine Class B Derivatives [C] . Yu Wang, Fanbo Wang, Libo Du International Conference on Material Science and Engineering . 2021

机译：基于罗丹明级B衍生物的荧光探针分子的合成与研究
5. Synthesis and Characterization of Novel Flavonoid-Based Fluorescent Sensors and Other Sensors with Excited State Intramolecular Proton Transfer for Biological Applications [D] . McDonald, Lucas J. 2018

机译：新型基于类黄酮的荧光传感器和其他具有激发态分子内质子转移的生物传感器的合成与表征
6. RBAP a Rhodamine B-Based Derivative: Synthesis Crystal Structure Analysis Molecular Simulation and Its Application as a Selective Fluorescent Chemical Sensor for Sn2+ [O] . Xiaofeng Bao, Xiaowei Cao, Xuemei Nie, 2014

机译：RBAP基于罗丹明B的衍生物：合成晶体结构分析分子模拟及其在Sn2 +的选择性荧光化学传感器中的应用
7. RBAP, a Rhodamine B-Based Derivative: Synthesis, Crystal Structure Analysis, Molecular Simulation, and Its Application as a Selective Fluorescent Chemical Sensor for Sn2+ [O] . Xiaofeng Bao, Xiaowei Cao, Xuemei Nie, 2014

机译：RBap，罗丹明B基衍生物：合成，晶体结构分析，分子模拟及其作为sn2 +选择性荧光化学传感器的应用
8. Reagents Based on Cyclopentadienyl Derivatives of the Group 14 Elements for the Synthesis of Indium(I) Derivatives. Crystal and Molecular Structure of In(C5H4SiMe3). [R] . Beachley, O. T., Lees, J. F., Glassman, T. E., 1990

机译：基于第14族元素的环戊二烯基衍生物的合成铟（I）衍生物的试剂。 In（C5H4sime3）的晶体和分子结构。

RBAP, a Rhodamine B-Based Derivative: Synthesis, Crystal Structure Analysis, Molecular Simulation, and Its Application as a Selective Fluorescent Chemical Sensor for Sn2+

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