Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives

S. R. Sritharan; B. A. Hussein; D. D. Machin; M. A. El-Aooiti; J. A. Adjei; J. K. Singh; J. T. H. Pau; J. S. Dhindsa; A. J. Lough; B. D. Koivisto

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Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives

机译：管理亲核加成反应以调节2-取代的五甲基BODIPY衍生物的物理性质

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The synthesis and characterization of a family of 2-substituted BODIPY dyes are reported herein. The dyes have been prepared using nucleophilic addition reactions (Wittig reactions, imine, Knoevenagel & aldol condensations) which are typically more challenging for BODIPY ring systems. Structure–property relationships have also been delineated by evaluating the physicochemical properties including; absorption & emission spectroscopy, electrochemical studies (CV, DPV) and theoretical calculations (TD-DFT).

机译：本文报道了2-取代的BODIPY家族的合成和表征。染料是使用亲核加成反应（维蒂希反应，亚胺，Knoevenagel和羟醛缩合反应）制备的，通常对BODIPY环系统而言更具挑战性。通过评估其理化性质还可以描述结构-性质的关系。吸收和发射光谱，电化学研究（CV，DPV）和理论计算（TD-DFT）。

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《RSC Advances》 |2017年第15期|共5页
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S. R. Sritharan; B. A. Hussein; D. D. Machin; M. A. El-Aooiti; J. A. Adjei; J. K. Singh; J. T. H. Pau; J. S. Dhindsa; A. J. Lough; B. D. Koivisto;
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7. Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives [O] . S. R. Sritharan, B. A. Hussein, D. D. Machin, 2017

机译：管理亲核的添加反应，以调整2取代的五甲基甲基小径衍生物的物理性质

Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives

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