Thermally robust: triarylsulfonium ionic liquids stable in air for 90 days at 300 °C

Benjamin Siu; Cody G. Cassity; Adela Benchea; Taylor Hamby; Jeffrey Hendrich; Katie J. Strickland; Andrzej Wierzbicki; Richard E. Sykora; E. Alan Salter; Richard A. OBrien; Kevin N. West; James H. Davis

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Thermally robust: triarylsulfonium ionic liquids stable in air for 90 days at 300 °C

机译：耐热性强：三芳基ulf离子液体在300°C的空气中可稳定90天

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Select triarylsulfonium salts constitute ionic liquids with outstanding long-term, high-temperature aerobic stability (no mass loss in 90 days at 300 °C in air), making them among the most thermally stable organic materials known. A detailed analysis of their thermophysical properties reveals that lowering melting points in these salts by increasing ion size or lowering ion symmetry cannot be assumed, but remains an iterative process.

机译：精选的三芳基ulf盐构成离子液体，具有出色的长期高温有氧稳定性（在300°C的空气中90天无质量损失），使其成为已知的最热稳定的有机材料。对它们的热物理性质的详细分析表明，不能假设通过增加离子尺寸或降低离子对称性来降低这些盐的熔点，但仍然是一个迭代过程。

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《RSC Advances》 |2017年第13期|共8页
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Benjamin Siu; Cody G. Cassity; Adela Benchea; Taylor Hamby; Jeffrey Hendrich; Katie J. Strickland; Andrzej Wierzbicki; Richard E. Sykora; E. Alan Salter; Richard A. OBrien; Kevin N. West; James H. Davis;
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1. Thermally robust: triarylsulfonium ionic liquids stable in air for 90 days at 300 °C [J] . Benjamin Siu, Cody G. Cassity, Adela Benchea, RSC Advances . 2017,第13期

机译：耐热性强：三芳基ulf离子液体在300°C的空气中可稳定90天
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Thermally robust: triarylsulfonium ionic liquids stable in air for 90 days at 300 °C

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