Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(I) trifluoromethanethiolate and selectfluor

Bin He; Zhiwei Xiao; Hao Wu; Yong Guo; Qing-Yun Chen; Chao Liu

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Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(I) trifluoromethanethiolate and selectfluor

机译：烷基羧酸与三氟甲硫醇银（I）和Selectfluor的氧化脱羧自由基三氟甲硫基化

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A straightforward silver-mediated oxidative decarboxylative radical trifluoromethylthiolation reaction of aliphatic carboxylic acid is described. This reaction operates under mild conditions and allows the synthesis of various valuable alkyltrifluoromethylthioethers from abundant alkyl carboxylic acids and convenient nucleophilic AgSCF₃ reagent. It provides a practical and efficient approach for the preparation of alkyltrifluoromethylthioethers.

机译：描述了脂肪族羧酸的直接的银介导的氧化脱羧自由基三氟甲基硫醇化反应。该反应在温和的条件下进行，可以从丰富的烷基羧酸和方便的亲核AgSCF _{3 试剂合成各种有价值的烷基三氟甲基硫醚。它为制备烷基三氟甲基硫醚提供了一种实用而有效的方法。}

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《RSC Advances》 |2017年第2期|共4页
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Bin He; Zhiwei Xiao; Hao Wu; Yong Guo; Qing-Yun Chen; Chao Liu;
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中图分类化学;
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1. Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(I) trifluoromethanethiolate and selectfluor [J] . Bin He, Zhiwei Xiao, Hao Wu, RSC Advances . 2017,第2期

机译：烷基羧酸与三氟甲硫醇银（I）和Selectfluor的氧化脱羧自由基三氟甲硫基化
2. Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids [J] . Candish Lisa, Pitzer Lena, Gomez-Suarez Adrian, Chemistry: A European journal . 2016,第14期

机译：可见光促进烷基羧酸的脱羧二和三氟甲基硫醇化
3. Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids [J] . Candish Lisa, Pitzer Lena, Gomez-Suarez Adrian, Chemistry: A European journal . 2016,第14期

机译：可见光促进烷基羧酸的脱羧二和三氟甲基硫醇化
4. Organocatalytic Decarboxylative Functionalization of Carboxylic Acids [C] . Kazumasa Kitahara, Misaki Katada, Seiji Iwasa 日本化学会春季年会講演予稿集 . 2018

机译：有机催化脱羧羧酸脱羧官能化
5. Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids [D] . Ju, Lin 2015

机译：铜介导的氧化脱羧偶联反应：以三氟乙酸为CF3源的杂芳烃C-H键的三氟甲基化和苯并恶唑与苯甲酸的C-H芳基化
6. Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process [O] . Jiancan Zhao, Hong Fang, Jianlin Han, 2013

机译：通过自由基过程铁催化的环烷烃与芳基乙烯基羧酸的脱羧烯基化
7. Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(i) trifluoromethanethiolate and selectfluor [O] . Bin He, Zhiwei Xiao, Hao Wu, 2017

机译：用银（I）三氟甲酰乙烯酸酯和选择氟乙烯基羧酸烷基羧酸的氧化脱羧的自由基三氟甲基化。

Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(I) trifluoromethanethiolate and selectfluor

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