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Highly (100)-oriented CH3NH3PbI3(Cl) perovskite solar cells prepared with NH4Cl using an air blow method

机译:用鼓风法用NH4Cl制备的高度(100)取向的CH3NH3PbI3(Cl)钙钛矿型太阳能电池

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The effects of adding NH _(4) Cl via an air blow process on CH _(3) NH _(3) PbI _(3) (Cl) perovskite solar cells were investigated. CH _(3) NH _(3) PbI _(3) (Cl) solar cells containing various amounts of NH _(4) Cl were fabricated by spin-coating. The microstructures of the resulting cells were investigated by X-ray diffraction, optical microscopy, and scanning electron microscopy. The current density–voltage characteristics of the cell were improved by adding an appropriate amount of NH _(4) Cl and air blowing, which increased the photoconversion efficiency to 14%. Microstructure analysis indicated that the perovskite layer contained dense grains with strong (100) orientation, as a result of NH _(4) Cl addition and air blowing. The ratio of the (100)/(210) reflection intensities for the perovskite crystals was 2000 times higher than that of randomly oriented grains. The devices were stable when stored in ambient air for two weeks.
机译:研究了通过吹气过程添加NH _(4)Cl对CH _(3)NH _(3)PbI _(3)(Cl)钙钛矿型太阳能电池的影响。通过旋涂法制备了含有各种数量的NH _(4)Cl的CH _(3)NH _(3)PbI _(3)(Cl)太阳能电池。通过X射线衍射,光学显微镜和扫描电子显微镜研究所得细胞的微观结构。通过添加适量的NH _(4)Cl和吹气可改善电池的电流密度-电压特性,从而将光转换效率提高到14%。微观结构分析表明,由于添加了NH _(4)Cl和吹气,钙钛矿层含有致密(100)取向的晶粒。钙钛矿晶体的(100)/(210)反射强度之比比随机取向的晶粒高2000倍。该设备在环境空气中存放两周后保持稳定。

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