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Highly (100)-oriented CH3NH3PbI3(Cl) perovskite solar cells prepared with NH4Cl using an air blow method

机译:高度(100)的CH3NH3PBI3(CL)使用空气吹法使用NH4CL制备的钙钛矿太阳能电池

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摘要

The effects of adding NH4Cl via an air blow process on CH3NH3PbI3(Cl) perovskite solar cells were investigated. CH3NH3PbI3(Cl) solar cells containing various amounts of NH4Cl were fabricated by spin-coating. The microstructures of the resulting cells were investigated by X-ray diffraction, optical microscopy, and scanning electron microscopy. The current density-voltage characteristics of the cell were improved by adding an appropriate amount of NH4Cl and air blowing, which increased the photoconversion efficiency to 14%. Microstructure analysis indicated that the perovskite layer contained dense grains with strong (100) orientation, as a result of NH4Cl addition and air blowing. The ratio of the (100)/(210) reflection intensities for the perovskite crystals was 2000 times higher than that of randomly oriented grains. The devices were stable when stored in ambient air for two weeks.
机译:研究了通过吹气过程加入NH 4 Cl在CH3NH3PBI3(CL)钙钛矿太阳能电池上的影响。 通过旋涂制备含有各种量NH 4 Cl的CH 3 NH 3PBI3(CL)太阳能电池。 通过X射线衍射,光学显微镜和扫描电子显微镜研究所得细胞的微观结构。 通过加入适量的NH 4 Cl和空气吹气,可以提高电池的电流密度 - 电压特性,这增加了光电转换效率至14%。 微观结构分析表明,由于NH4CL加成和空气吹气,钙钛矿层含有强(100)取向的致密晶粒。 钙钛矿晶体的(100)/(210)反射强度的比例比随机取向晶粒的比例高2000倍。 当在环境空气中储存两周时,器件稳定。

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  • 来源
    《RSC Advances》 |2018年第19期|共7页
  • 作者单位

    Univ Shiga Prefecture Dept Mat Sci 2500 Hassaka Hikone Shiga 5228533 Japan;

    Univ Shiga Prefecture Dept Mat Sci 2500 Hassaka Hikone Shiga 5228533 Japan;

    Univ Shiga Prefecture Dept Mat Sci 2500 Hassaka Hikone Shiga 5228533 Japan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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