Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins

Dong Liang; Yan Wang; Sifan Wang; Chengkun Song; Yonghe Shi; Qinghao Liu; Hailin Zhu; Xia Li; Laishuan Liu; Na Zhu

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Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins

机译：硅骨架中密闭的多金属氧酸盐离子液体，用于环境友好的烯烃不对称二羟基化反应

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Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant “chiral pools” of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media.

机译：烯烃的不对称二羟基化反应可通过生态友好且持久的催化剂直接制备高收率的手性1,2-二醇，其中将多金属氧酸盐离子液体的丰富“手性库”目标设计为硅骨架（POM-ILS）并在水性介质中稳定。

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《RSC Advances》 |2019年第11期|共5页
作者
Dong Liang; Yan Wang; Sifan Wang; Chengkun Song; Yonghe Shi; Qinghao Liu; Hailin Zhu; Xia Li; Laishuan Liu; Na Zhu;
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1. Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins [J] . Liang Dong, Wang Yan, Wang Sifan, RSC Advances . 2019,第11期

机译：用于环保不对称二氢烯烃的硅框架中孔隙孔型多氧乙烯 - 离子液体
2. Catalytic asymmetric reactions using environmentally friendly reagents and catalyst:Asymmetric synthesis versus kinetic resolution [J] . Kiyoshi Tomioka Pure and Applied Chemistry . 2006,第11期

机译：使用环保试剂和催化剂的催化不对称反应：不对称合成与动力学拆分
3. Ruthenium-Catalysed Olefin Metathesis in Environmentally Friendly Solvents: 2-Methyltetrahydrofuran Revisited [J] . Micha? Smoleń, Anna Marczyk, Wioletta Ko?nik, European journal of organic chemistry . 2019,第4期

机译：环保溶剂中的钌催化烯烃复分解：重新审视2-甲基四氢呋喃
4. Safe and environmentally friendly large power transformers with ester successful introduction of ester liquids at the 420 kV transmission level [C] . G. J. Pukel, G. Fleck, H. Pregartner, IEEE electrical insulation conference . 2016

机译：安全环保的大型电力变压器，以酯形式成功引入420 kV输电等级的酯液体
5. Polymer-Decorated Cellulose Nanocrystals as Environmentally Friendly Additives for Olefin-Based Drilling Fluids [O] . José Aurélio Pinheiro, Nívia do Nascimento Marques, Marcos Antônio Villetti, 2021

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6. Socialization of Tofu Liquid Waste Management (Whey Tofu) Becomes Biogas as Alternative Energy Reserves in the Framework of Creating an Environmentally Friendly Industry [O] . Nely Ana Mufarida, Orisanto Darma Setiawan 2020

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Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins

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