One-pot synthesis of chiral alcohols from alkynes by CF3SO3H/ruthenium tandem catalysis

Huan Liu; Sensheng Liu; Haifeng Zhou; Qixing Liu; Chunqin Wang

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One-pot synthesis of chiral alcohols from alkynes by CF3SO3H/ruthenium tandem catalysis

机译：CF3SO3H /钌串联催化从炔烃一锅法合成手性醇

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A practical one-pot synthesis of chiral alcohols from readily available alkynes via tandem catalysis by the combination of CF _(3) SO _(3) H and a fluorinated chiral diamine Ru( II ) complex in aqueous CF _(3) CH _(2) OH is described. Very interestingly, the combination of fluorinated catalysts and solvent exhibits a positive fluorine effect on the reactivity and enantioselectivity. A range of chiral alcohols with wide functional group tolerance was obtained in high yield and excellent stereoselectivity under simple and mild conditions.

机译：通过CF_（3）SO_（3）H和氟化CF_（3）CH_的氟化手性二胺Ru（II）配合物的组合催化，从串联反应中容易地从炔烃中一手法合成手性醇（2）描述了OH。非常有趣的是，氟化催化剂和溶剂的组合对反应性和对映选择性表现出积极的氟效应。在简单温和的条件下，可以高收率和优异的立体选择性获得一系列具有宽泛的官能团耐受性的手性醇。

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《RSC Advances》 |2018年第27期|共4页
作者
Huan Liu; Sensheng Liu; Haifeng Zhou; Qixing Liu; Chunqin Wang;
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中图分类化学;
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1. One-pot synthesis of chiral alcohols from alkynes by CF3SO3H/ruthenium tandem catalysis [J] . Liu Huan, Liu Sensheng, Zhou Haifeng, RSC Advances . 2018,第27期

机译：CF3SO3H / Ruthenium催化来自炔烃的手性醇的一锅合成
2. One-pot synthesis of chiral alcohols from alkynes by CF3SO3H/ruthenium tandem catalysis [J] . Huan Liu, Sensheng Liu, Haifeng Zhou, RSC Advances . 2018,第27期

机译：CF3SO3H /钌串联催化从炔烃一锅法合成手性醇
3. One-Pot Synthesis of Quinoline Derivatives Directly from Terminal Alkynes via Sequential Ruthenium(II) and Acid Catalysis [J] . Min Zhang, Thierry Roisnel, Pierre H. Dixneuf Advanced synthesis & catalysis . 2010,第11a12期

机译：通过连续钌（II）和酸催化直接从末端炔烃一锅法合成喹啉衍生物
4. ENANTIOCOMPLEMENTARY SYNTHESIS OF CHIRAL ALCOHOLS COMBINING PHOTOCATALYSIS AND WHOLE-CELL BIOCATALYSIS IN A ONE-POT CASCADE PROCESS [C] . Yongzhen Peng, Jian Xu, Xianfu Lin, Conference on biochemical and molecular engineering . 2019

机译：一锅级联过程中光催化与全细胞生物催化相结合的手性醇的对映体合成
5. Part I. One-pot synthesis of secondary alcohols and one-pot asymmetric synthesis of secondary propargylic alcohols. Part II. Redox isomerization of secondary propargylic alcohols to enones. Part III. Synthesis study towards C9-C14 fragment of (+)-discodermolide. Part IV. Asymmetric synthesis of anti, anti-stereotriad building blocks for polypropionate natural products [D] . Xie, Qiuzhe 2007

机译：第一部分：仲醇的一锅法合成和仲炔丙醇的一锅法不对称合成。第二部分仲炔丙醇的氧化还原异构化为烯酮。第三部分（+）-discodermolide C9-C14片段的合成研究。第四部分聚丙烯酸酯天然产物的抗，抗立体三环构建基的不对称合成
6. Highly Enantioselective One-Pot Synthesis of Chiralβ-Heterosubstituted Alcohols via Ruthenium–Prolinamide-CatalyzedAsymmetric Transfer Hydrogenation [O] . VijyeshK. Vyas, Prasenjit Srivastava, Prachi Bhatt, 2018

机译：手性高对映选择性一锅合成钌-脯氨酰胺催化的β-杂醇不对称转移加氢
7. Highly Enantioselective One-Pot Synthesis of Chiral β-Heterosubstituted Alcohols via Ruthenium–Prolinamide-Catalyzed Asymmetric Transfer Hydrogenation [O] . Vijyesh K. Vyas, Prasenjit Srivastava, Prachi Bhatt, 2018

机译：通过钌 - 脯氨酰胺催化的不对称转移氢化高度致癌的手性β-异质取代醇的单壶合成

One-pot synthesis of chiral alcohols from alkynes by CF3SO3H/ruthenium tandem catalysis

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