• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Indium-based metal–organic frameworks as catalysts: synthesis of 2-nitro-3-arylimidazo[1,2-a]pyridines via oxidative amination under air using MIL-68(In) as an effective heterogeneous catalyst
【24h】

Indium-based metal–organic frameworks as catalysts: synthesis of 2-nitro-3-arylimidazo[1,2-a]pyridines via oxidative amination under air using MIL-68(In) as an effective heterogeneous catalyst

机译：铟基金属有机框架作为催化剂：MIL-68在空气中通过氧化胺化合成2-硝基-3-芳基咪唑并[1,2- a ]吡啶 （In）作为有效的多相催化剂

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The metal–organic framework MIL-68(In) has emerged as a productive heterogeneous catalyst for the synthesis of 2-nitro-3-arylimidazo[1,2-a]pyridines via oxidative amination between 2-aminopyridines and nitroalkenes using air as an oxidation agent. The catalyst displayed impressively higher efficiency for the generation of 2-nitro-3-arylimidazo[1,2-a]pyridines than various other MOFs and several common homogeneous catalysts. Heterogeneous catalysis was verified for the reaction of 2-aminopyridines with nitroalkenes employing the framework-based catalyst. It was possible to collect and reuse the catalyst for the production of 2-nitro-3-arylimidazo[1,2-a]pyridines without a pronounced deterioration in catalytic efficiency. To the best of our knowledge, the preparation of 2-nitro-3-arylimidazo[1,2-a]pyridines has not been formerly conducted utilizing heterogeneous catalysts. Furthermore, indium-based catalysts were not previously employed for this transformation.
机译：金属-有机骨架MIL-68（In）已成为一种生产多相催化剂，可用于合成2-硝基-3-芳基咪唑并[1,2- a ]吡啶 。使用空气作为氧化剂，在2-氨基吡啶和硝基烯烃之间进行氧化胺化。与其他各种MOF和几种常见的均相催化剂相比，该催化剂显示出2-硝基-3-芳基咪唑并[1,2- a ]吡啶的惊人高效率。使用基于骨架的催化剂，对2-氨基吡啶与硝基烯烃的反应进行了非均相催化。可以收集并再利用催化剂生产2-硝基-3-芳基咪唑并[1,2- a ]吡啶，而不会明显降低催化效率。据我们所知，2-硝基-3-芳基咪唑并[1,2- a ]吡啶的制备以前并未使用非均相催化剂进行。此外，以前没有将铟基催化剂用于该转化。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号