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Room temperature oxidative desulfurization with MoO3 subnanoclusters supported on MCM-41

机译:MCM-41支持的MoO3亚纳簇的室温氧化脱硫

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Subnano MoO _(3) /MCM-41 was successfully prepared through doping (NH _(4) ) _(6) Mo _(7) O _(24) in the synthesis process of MCM-41. The morphology of MoO _(3) /MCM-41 was visually observed by TEM and HADDF-STEM. N _(2) sorption, XPS and Raman were further applied to investigate the structure of the material. MoO _(3) /MCM-41 was used in the oxidative desulfurization process with tert -butyl hydroperoxide as oxidant. MoO _(3) /MCM-41 showed outstanding catalytic activity and recycling ability at room temperature.
机译:在MCM-41的合成过程中,通过掺杂(NH _(4)_(6)Mo _(7)O _(24)成功地制备了Subnano MoO _(3)/ MCM-41。通过TEM和HADDF-STEM目测观察到MoO_(3)/ MCM-41的形态。 N_(2)吸附,XPS和拉曼进一步研究材料的结构。 MoO_(3)/ MCM-41用于叔丁基过氧化氢作为氧化剂的氧化脱硫工艺。 MoO_(3)/ MCM-41在室温下显示出出色的催化活性和再循环能力。

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