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Temperature-triggered reversible breakdown of polymer-stabilized olive–silicone oil Janus emulsions

机译:聚合物稳定的橄榄油-硅油Janus乳液的温度触发可逆分解

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A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly( N , N -diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room temperature and could be destabilized on demand upon heating to the transition temperature of the polymeric stabilizer. Time-dependent light micrographs demonstrate the temperature-induced breakdown of the Janus droplets, which opens new aspects of application, for instance in biocatalysis.
机译:成功地采用了一步式中能振动乳化法生产了由带有0.7 mol%油酰基侧链的聚(N,N-二乙基丙烯酰胺)稳定化的热响应性基于橄榄/硅氧烷的Janus乳液。完全吞噬的乳液液滴在室温下保持稳定,并在加热至聚合物稳定剂的转变温度时可根据需要使其不稳定。随时间变化的光学显微照片显示了Janus液滴的温度诱导击穿,这为应用提供了新的方面,例如在生物催化中。

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