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Electro-deposition of bactericidal and corrosion-resistant hydroxyapatite nanoslabs

机译:电解和抗腐蚀羟基磷灰石纳米板的电沉积

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Herein, nanoscale hydroxyapatite (HA) with a slab-like morphology was synthesized, and its size was calculated to be in the range of 80–150 nm, as confirmed via scanning electron microscopy (SEM) and atomic force microscopy (AFM). The nanoscale HA with a slab-like structure has been referred as HA nanoslabs in the manuscript. The composition, crystallinity, wettability, bacterial resistance porosity, surface roughness and corrosion resistance of these HA nanoslabs were studied using energy dispersive spectroscopy (EDAX), X-ray diffraction (XRD), contact angle, colony count BET analyzer and profilometer and polarization techniques, respectively. The contact angle of the HA nanoslabs was found to be 22.6°, which indicated the hydrophilic nature of these nanoslabs. Their bacterial resistance was studied against the Salmonella typhi strain, and it was found that in the presence of the HA nanoslabs, the growth of the bacteria was hindered. For the corrosion resistance study, the HA nanoslabs were electro-deposited on a titanium alloy, used as a substrate. The deposition was carried out at varying currents, viz , 1 mA, 3 mA and 5 mA. The open circuit potential (OCP) and polarization were used for the estimation of the corrosion resistance of the bare and coated substrates. The corrosion potential started shifting towards noble potential, and the current density started decreasing with an increase in the electrochemical deposition current. This indicated good corrosion resistance of these nanoslabs.
机译:本文中,通过扫描电子显微镜(SEM)和原子力显微镜(AFM)证实,合成了具有平板状形态的纳米级羟基磷灰石(HA),其尺寸经计算在80–150 nm范围内。手稿中具有板状结构的纳米级HA被称为HA纳米板。使用能量色散光谱(EDAX),X射线衍射(XRD),接触角,菌落计数BET分析仪,轮廓仪和极化技术研究了这些HA纳米板的组成,结晶度,润湿性,细菌抵抗性孔隙率,表面粗糙度和抗腐蚀性。 , 分别。发现HA纳米板的接触角为22.6°,这表明这些纳米板的亲水性。研究了它们对伤寒沙门氏菌的耐药性,发现在HA纳米片的存在下,细菌的生长受到了阻碍。为了进行耐腐蚀研究,将HA纳米板电沉积在用作基材的钛合金上。沉积在变化的电流下进行,即1mA,3mA和5mA。开路电势(OCP)和极化用于估计裸露和涂层基材的耐腐蚀性。腐蚀势开始向贵势转移,电流密度随着电化学沉积电流的增加而开始下降。这表明这些纳米板具有良好的耐腐蚀性。

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