Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums

Lianbao Ye; Chao Han; Peiqi Shi; Wei Gao; Wenjie Mei

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Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums

机译：铜催化二芳基碘鎓的羟基化反应合成苯酚和二芳基醚衍生物

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A copper-catalysed hydroxylation of diaryliodoniums to generate phenols and diaryl ethers is reported. This method allows the synthesis of diversely functionalized phenols under mild reaction conditions without the need for a strong inorganic base or an expensive noble-metal catalyst. Significantly, convenient application of diaryliodoniums is demonstrated in the preparation of diaryl ethers in a one-pot operation.

机译：据报道，铜催化的二芳基碘鎓的羟基化反应生成酚和二芳基醚。该方法无需温和的无机碱或昂贵的贵金属催化剂即可在温和的反应条件下合成各种官能化的苯酚。重要的是，在一锅操作中制备二芳基醚证明了二芳基碘鎓的方便应用。

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《RSC Advances》 |2019年第37期|共5页
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Lianbao Ye; Chao Han; Peiqi Shi; Wei Gao; Wenjie Mei;
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中图分类化学;
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1. Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums [J] . Ye Lianbao, Han Chao, Shi Peiqi, RSC Advances . 2019,第37期

机译：铜催化通过二芳烃的羟基化合成苯酚和二芳基醚衍生物
2. Copper-catalyzed hydroxylation of aryl halides: efficient synthesis of phenols, alkyl aryl ethers and benzofuran derivatives in neat water [J] . Wang Yangxin, Zhou Chunshan, Wang Ruihu Green chemistry . 2015,第7期

机译：铜催化的芳基卤的羟基化：在纯净水中高效合成苯酚，烷基芳基醚和苯并呋喃衍生物
3. Synthesis of Phenol, Aromatic Ether, and Benzofuran Derivatives by Copper-Catalyzed Hydroxylation of Aryl Halides [J] . Dongbing Zhao, Ningjie Wu, Shuai Zhang Angewandte Chemie . 2009,第46期

机译：铜催化芳基卤化物的羟基化反应合成苯酚，芳族醚和苯并呋喃衍生物
4. Copper-Catalyzed Synthesis of Unsymmetrical Organosulfide Compounds Using Diaryl Disulfides and Organoboronic Acids [C] . Nobukazu Taniguchi Symposium on Organometallic Chemistry . 2006

机译：使用二芳基二硫化物和有机硼酸的铜催化合成非对称有机硫化物化合物
5. Total syntheses of ustiloxin D, ustiloxin F and analogs via an unprecedented copper-catalyzed ethynyl aziridine ring-opening reaction by phenol derivatives. [D] . Li, Pixu. 2005

机译：通过苯酚衍生物通过前所未有的铜催化的乙炔基氮丙啶开环反应，总合成ustiloxin D，ustiloxin F和类似物。
6. Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers [O] . Debabrata Maiti, Stephen L. Buchwald -1

机译：酚类的铜催化的芳基：空间位阻和杂二芳基醚的合成
7. Room temperature, metal-free synthesis of diaryl ethers with use of diaryliodonium salts [O] . Jalalian, Nazli, Ishikawa, Eloisa E., Silva Jr., Luiz F., 2011

机译：使用二芳基碘鎓盐在室温下无金属合成二芳基醚

Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums

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