Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

Yana Karslyan; Frederick V. Sloop; Laetitia H. Delmau; Bruce A. Moyer; Ilja Popovs; Alena Paulenova; Santa Jansone-Popova

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Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

机译：在烃类溶剂中用双-内酰胺-1,10-菲咯啉配体螯合三价valent和硝酸镧

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Efficient separation of minor actinides and lanthanides from used nuclear fuel could potentially lead to the development of sustainable nuclear fuel cycles. Herein, we report an in-depth study on selectivity and speciation in the extraction of the trivalent minor actinide Am and rare earth metal ions with a pre-organized phenanthroline-based ligand in a hydrocarbon solvent system relevant to nuclear fuel reprocessing. The 1?:?1 and 2?:?1 ligand-to-metal complexes dominate the speciation in the organic solvent over a range of ligand-to-metal concentrations, as evidenced by experimental data and supported by modeling.

机译：从用过的核燃料中有效分离次act系元素和镧系元素可能会导致发展可持续的核燃料循环。本文中，我们报告了在与核燃料后处理有关的烃溶剂系统中，用预先组织的菲咯啉基配体萃取三价次minor系元素Am和稀土金属离子的选择性和形态的深入研究。实验数据证明并通过建模证明，在一定范围的配体-金属浓度范围内，1α：？1和2α：？1配体与金属的络合物在有机溶剂中占主导地位。

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《RSC Advances》 |2019年第46期|共5页
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Yana Karslyan; Frederick V. Sloop; Laetitia H. Delmau; Bruce A. Moyer; Ilja Popovs; Alena Paulenova; Santa Jansone-Popova;
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1. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [J] . RSC Advances . 2019,第46期

机译：用双-Nactam -1,10-菲咯啉配体在烃溶剂中螯合三价亚美和镧硝酸盐的固化
2. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [J] . Yana Karslyan, Frederick V. Sloop, Laetitia H. Delmau, RSC Advances . 2019,第46期

机译：在烃类溶剂中用双-内酰胺-1,10-菲咯啉配体螯合三价valent和硝酸镧
3. Complexation of trivalent americium and lanthanides with terdentate 'N' donor ligands: the role of rigidity in the ligand structure [J] . Arunasis Bhattacharyya, Trilochan Gadly, Priyanath Pathak, Dalton transactions: An international journal of inorganic chemistry . 2014,第32期

机译：三价a和镧系元素与齿状“ N”供体配体的络合：刚性在配体结构中的作用
4. Synthesis, Characterization and Electrical Conductivity of Mixed-ligand 7, 7, 8, 8-Tetracyanoquinodimethaneand 1, 10-Phenanthroline Complexes of Lanthanide Perchlorate [C] . Zheng Xueqin International conference on rare earth development and application;ICRE'2001 . 2001

机译：高氯酸镧系元素的配体7、7、8、8-四苯甲基氨基喹二甲烷和1,10-菲咯啉配合物的合成，表征和电导率
5. The Coordination Chemistry of the Janus-head Ligand Tris(2-pyridyl)phosphine and Its Oxide with Nitrates of Divalent Late First Row Transition Metals and Trivalent Lanthanides. [D] . Pericic, Danijel Josip. 2014

机译：Janus头配体三（2-吡啶基）膦及其氧化物与二价晚排第一过渡金属和三价镧系元素的硝酸盐的配位化学。
6. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [O] . Yana Karslyan, Frederick V. Sloop, Laetitia H. Delmau, 2019

机译：用双-Nactam -1,10-菲咯啉配体在烃溶剂中螯合三价亚美和镧硝酸盐的固化
7. Solvent extraction separation of trivalent lanthanide and actinide ions using an aqueous aminomethanediphosphonic acid. [R] . Jensen, M. P. 1998

机译：使用氨基甲烷二膦酸水溶液萃取分离三价镧系元素和act系元素离子。

Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

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