Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

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Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

机译：用双-Nactam -1,10-菲咯啉配体在烃溶剂中螯合三价亚美和镧硝酸盐的固化

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Efficient separation of minor actinides and lanthanides from used nuclear fuel could potentially lead to the development of sustainable nuclear fuel cycles. Herein, we report an in-depth study on selectivity and speciation in the extraction of the trivalent minor actinide Am and rare earth metal ions with a pre-organized phenanthroline-based ligand in a hydrocarbon solvent system relevant to nuclear fuel reprocessing. The 1 : 1 and 2 : 1 ligand-to-metal complexes dominate the speciation in the organic solvent over a range of ligand-to-metal concentrations, as evidenced by experimental data and supported by modeling.

机译：从使用的核燃料中有效分离少量弧菌和镧可能可能导致可持续核燃料循环的发展。在此，我们报告了对与核燃料再处理相关的烃溶剂系统中的预组织的菲芳啉基配体提取三价少量Actinide AM和稀土金属离子中的选择性和形态的深入研究。 1：1和2：1配体 - 金属配合物在一系列配体 - 金属浓度上占据了有机溶剂中的物质，如实验数据所证明并通过建模支持。

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《RSC Advances》 |2019年第46期|共5页
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1. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [J] . RSC Advances . 2019,第46期

机译：用双-Nactam -1,10-菲咯啉配体在烃溶剂中螯合三价亚美和镧硝酸盐的固化
2. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [J] . Yana Karslyan, Frederick V. Sloop, Laetitia H. Delmau, RSC Advances . 2019,第46期

机译：在烃类溶剂中用双-内酰胺-1,10-菲咯啉配体螯合三价valent和硝酸镧
3. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [J] . Yana Karslyan, Frederick V. Sloop, Laetitia H. Delmau, RSC Advances . 2019,第46期

机译：在烃类溶剂中用双-内酰胺-1,10-菲咯啉配体螯合三价valent和硝酸镧
4. Synthesis, Characterization and Electrical Conductivity of Mixed-ligand 7, 7, 8, 8-Tetracyanoquinodimethaneand 1, 10-Phenanthroline Complexes of Lanthanide Perchlorate [C] . Zheng Xueqin International conference on rare earth development and application;ICRE'2001 . 2001

机译：高氯酸镧系元素的配体7、7、8、8-四苯甲基氨基喹二甲烷和1,10-菲咯啉配合物的合成，表征和电导率
5. The Coordination Chemistry of the Janus-head Ligand Tris(2-pyridyl)phosphine and Its Oxide with Nitrates of Divalent Late First Row Transition Metals and Trivalent Lanthanides. [D] . Pericic, Danijel Josip. 2014

机译：Janus头配体三（2-吡啶基）膦及其氧化物与二价晚排第一过渡金属和三价镧系元素的硝酸盐的配位化学。
6. Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent [O] . Yana Karslyan, Frederick V. Sloop, Laetitia H. Delmau, 2019

机译：用双-Nactam -1,10-菲咯啉配体在烃溶剂中螯合三价亚美和镧硝酸盐的固化
7. Solvent extraction separation of trivalent lanthanide and actinide ions using an aqueous aminomethanediphosphonic acid. [R] . Jensen, M. P. 1998

机译：使用氨基甲烷二膦酸水溶液萃取分离三价镧系元素和act系元素离子。

Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

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