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Carbon Dioxide Laser Supersonic Drawing Nanofiber Sheet for Extraction of Polycyclic Aromatic Hydrocarbons in Water Samples

机译:二氧化碳激光超声波拉伸纳米纤维片,用于在水样中提取多环芳烃

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An extraction capillary packed with a polyethylene terephthalate nanofiber-sheet was applied for the extraction of five water soluble polycyclic aromatic hydrocarbons (PAHs, including naphthalene (Nap), fluorene (Flu), phenanthrene (Phe), fluoranthene (Flt), and pyrene (Pyr)), in water samples. The extracted PAHs were eluted with acetonitrile, and on-line injected into a high-performance liquid chromatographic system coupled with a fluorescence detector. The limit of detections of the method for Nap, Flu, Phe, Flt, and Pyr were 1.0, 1.0, 0.2, 0.5, and 0.2 ng/mL, respectively, at a sample loading volume of 1.0 mL. The spiked recoveries of the analyte PAHs were in the range of 97.3 to 102% upon spiking the PAHs into tap water and river water samples.
机译:施用用聚对苯二甲酸乙二醇酯纳米纤维片的萃取毛细管用于提取五种水溶性多环芳烃(PAHS,包括萘(NAP),芴(流感),菲苯(PHE),氟蒽(FLT)和芘( Pyr)),在水样中。用乙腈洗脱萃取的PAHs,并注入与荧光检测器偶联的高性能液相色谱系统中的在线。在样品负载体积为1.0ml的样品中,分别在1.0,1.0,30,0.5和0.2ng / ml的样品中分别为1.0,1.0,0.2,0.5和0.2ng / ml检测。分析物PAH的尖刺回收率在捕捉PAHS进入水龙水和河水样品时,在97.3至102%的范围内。

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