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Performance of graphite felt as a cathode and anode in the electro-Fenton process

机译:石墨的性能毛毡作为电芬工艺中的阴极和阳极

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Choosing an electrode material with good performance and low cost is of great significance for the practical application of the electro-Fenton process. In this study, graphite felt was systematically studied to determine its application performance in an electro-Fenton system. The influence of operating parameters, pH and voltage, on the H _(2) O _(2) yield and the evolution of iron ions was investigated, which helped to select the optimal parameter values. The removal rate of methylene blue was 97.8% after 20 min electrolysis under the conditions of 7 V voltage and pH 3. Inhibition experiments showed the graphite felt E-Fenton system mainly relied on the indirect oxidation of ·OH and the direct oxidation of the graphite felt anode to degrade the methylene blue. The graphite felt showed good stability as a cathode during repeated use, but the anode conductivity and catalytic performance were decreased, and the adsorption performance was enhanced. Finally, the graphite felt electrode was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) and X-ray photoelectron spectroscopy (XPS) to preliminarily analyze the reason for the change in anode performance.
机译:选择具有良好性能和低成本的电极材料对于电气顿工艺的实际应用具有重要意义。在这项研究中,系统地研究了石墨毛毡,以确定其在电芬系统中的应用性能。研究了操作参数,pH和电压,在H _(2)O _(2)产率和铁离子的演变上的影响,有助于选择最佳参数值。在7V电压和pH 3的条件下20分钟电解后亚甲基蓝的去除率为97.8%。抑制实验表明石墨毛毡E-Fenton系统主要依赖于间接氧化·哦和石墨的直接氧化感觉阳极降解亚甲基蓝色。石墨毡在重复使用期间作为阴极显示出良好的稳定性,但阳极电导率和催化性能降低,并且增强了吸附性能。最后,石墨毡电极的特征在于扫描电子显微镜(SEM),X射线衍射(XRD),Brunauer-Emmett-Teller(Bet)和X射线光电子光谱(XPS),以预先分析变化的原因阳极性能。

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