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A study on the self-assembly mode and supramolecular framework of complexes of cucurbit[6]urils and 1-(4-methoxyphenyl)piperazine

机译：葫芦菌复合物自组装模式和超分子框架的研究及1-（4-甲氧基苯基）哌嗪

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Self-assembly between symmetrical dicyclohexyl-substituted cucurbit[6]uril (abbreviated as (CyH) _(2) Q[6] ) and cyclopentanocucurbit[6]uril ( CyP _(6) Q[6] ) as hosts and 1-(4-methoxyphenyl)piperazine ( MeOPP ) as a guest molecule has been studied by means of single-crystal X-ray diffraction analysis, NMR, MALDI-TOF mass spectrometry, and other characterization methods. The experimental results showed that the self-assembly was driven by the formation of exclusion complexes by the cucurbit[ n ]uril and the guest, that is, supramolecular interaction between the negative charge of the cucurbit[ n ]uril portals and a coordination polymer guest. Complexes were formed between the positive charge of the cucurbit[ n ]uril outer wall and inorganic anions, thus generating self-assemblies with multi-dimensional and multi-level supramolecular frameworks.
机译：对称二环己基取代的葫芦[6]尿素（缩写为（cyh）_（2）q [6]）和环比（Cyp _（6）q [6]）作为宿主和1- （4-甲氧基苯基）哌嗪（Meopp）作为客体分子，通过单晶X射线衍射分析，NMR，MALDI-TOF质谱和其他表征方法研究。实验结果表明，通过葫芦及客人的含油部形成排斥复合物的形成，即葫芦科门户的负电荷与协调聚合物客人之间的超分子相互作用，是自组装的推动。在葫芦[n]尿壁和无机阴离子的正电荷之间形成复合物，从而产生具有多维和多级超分子框架的自组装。

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