Selective, light-driven enzymatic dehalogenations of organic compounds

Bhavin Siritanaratkul; Shams T. A. Islam; Torsten Schubert; Cindy Kunze; Tobias Goris; Gabriele Diekert; Fraser A. Armstrong

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Selective, light-driven enzymatic dehalogenations of organic compounds

机译：有机化合物的选择性，光驱动的酶促脱卤

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Tetrachloroethene reductive dehalogenase (PceA), a corrinoid-containing enzyme from Sulfurospirillum multivorans , is highly active for the sequential reduction of the organohalide tetrachloroethene (PCE) to trichloroethene (TCE), then regiospecifically to cis -1,2-dichloroethene ( c DCE). We demonstrate direct electron transfer from graphite and semiconductor electrodes to PceA adsorbed onto the electrode surface. Colloidal TiO _(2) nanoparticles modified with PceA efficiently carry out the sequence of dehalogenation reactions under UV light irradiation.

机译：四氯乙烯还原脱氢酶（PCEA），来自硫括约年多元素的含致正甲酶，对于逐氯乙烯（PCE）与三氯乙烯（TCE）连续地降低，然后对CIS-1,2-二氯乙烯（C DCE）的顺序降低高度活性。。我们证明了从石墨和半导体电极到吸附在电极表面上的PCEA的直接电子转移。用PCEA改性的胶体TiO _（2）纳米粒子有效地在UV光照射下进行脱卤反应序列。

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《RSC Advances》 |2016年第88期|共5页
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Bhavin Siritanaratkul; Shams T. A. Islam; Torsten Schubert; Cindy Kunze; Tobias Goris; Gabriele Diekert; Fraser A. Armstrong;
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1. Selective, light-driven enzymatic dehalogenations of organic compounds [J] . Siritanaratkul Bhavin, Islam Shams T. A., Schubert Torsten, RSC Advances . 2016,第88期

机译：有机化合物的选择性，光驱动的酶促脱卤
2. Enzymatic dehalogenation of chlorinated nitroaromatic compounds. [J] . J Thiele, R Müller, F Lingens Applied and Environmental Microbiology . 1988,第5期

机译：氯化硝基芳族化合物的酶促脱卤作用。
3. An alpha-{P2W18O62}(6-)-Based Supramolecular Hybrid Inorganic-Organic Compound with Visible Light-Driven Photocatalytic Properties [J] . Zhu Xiaofei, Yang Yu, Jiang Ni, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第19期

机译：具有可见光驱动光催化特性的基于α-{P2W18O62}（6-）的超分子杂化无机有机化合物
4. DEHALOGENATION OF POLYHALOGENATED COMPOUNDS DISSOLVED IN ORGANIC SOLVENTS WITH THE HELP OF AOPS IN A TWO-PHASE SOLVENT-WATER SYSTEM UNDER THE INFLUENCE OF ULTRASOUND [C] . FRANTISEK KASTANEK, JIRI SOBEK, PETR KASTANEK International Conference on Environmental Science and Technology . 2011

机译：在超声波的影响下，在两相溶剂 - 水系统中的AOP中，在有机溶剂中溶解在有机溶剂中的多卤代化合物的脱氢。
5. Statistical Analysis to Identify Volatile Organic Compounds (VOCs) in Breath from Hypoglycemia and Development of Cross-Selective Nanosensors for Its Detection [D] . Daneshkhah, Ali. 2017

机译：统计分析鉴定挥发性有机化合物（VOCS）中的低血糖和交叉选择性纳米调传料的发育以进行检测
6. Enzymatic dehalogenation of chlorinated nitroaromatic compounds. [O] . J Thiele, R Müller, F Lingens 1988

机译：氯化硝基芳族化合物的酶促脱卤作用。
7. DHPA-Containing Cobalt-Based Redox Metal-Organic Cyclohelicates as Enzymatic Molecular Flasks for Light-Driven H2 Production [O] . Liang Zhao, Jian Wang, Pengyan Wu, 2017

机译：含DHPA的基于钴的氧化还原金属 - 有机环elicates作为酶分子烧瓶，用于光驱动的H2生产
8. Selective Reductions. XXI. 9-Borabicyclo(3.3.1) Nonane in Tetrahydrofuran as a New Selective Reducing Agent in Organic Synthesis. Reaction with Selected Organic Compounds Containing Representative Functional Groups. [R] . Brown, H. C., Krishnamurthy, S., Yoon, N. M. 1976

机译：选择性减少。 XXI。 9-Borabicyclo（3.3.1）四氢呋喃中的壬烷作为有机合成中的新型选择性还原剂。与含有代表性官能团的选定有机化合物反应。

Selective, light-driven enzymatic dehalogenations of organic compounds

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