Selective, light-driven enzymatic dehalogenations of organic compounds

Siritanaratkul Bhavin; Islam Shams T. A.; Schubert Torsten; Kunze Cindy; Goris Tobias; Diekert Gabriele; Armstrong Fraser A.

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Selective, light-driven enzymatic dehalogenations of organic compounds

机译：有机化合物的选择性，光驱动的酶促脱卤

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Tetrachloroethene reductive dehalogenase (PceA), a corrinoid-containing enzyme from Sulfurospirillum multivorans, is highly active for the sequential reduction of the organohalide tetrachloroethene (PCE) to trichloroethene (TCE), then regiospecifically to cis-1,2-dichloroethene (cDCE). We demonstrate direct electron transfer from graphite and semiconductor electrodes to PceA adsorbed onto the electrode surface. Colloidal TiO2 nanoparticles modified with PceA efficiently carry out the sequence of dehalogenation reactions under UV light irradiation.

机译：四氯乙烯还原脱氢酶（PCEA），含硫倍烃多转韦凡凡人的含有致正型酶，高度活跃，用于使有机卤代乙烯（PCE）与三氯乙烯（TCE）顺序降低，然后对CIS-1,2-二氯乙烯（CDCE）进行再现。我们证明了从石墨和半导体电极到吸附在电极表面上的PCEA的直接电子转移。用PCEA改性的胶体TiO2纳米颗粒有效地在UV光照射下进行脱卤反应的序列。

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来源
《RSC Advances》 |2016年第88期|共5页
作者
Siritanaratkul Bhavin; Islam Shams T. A.; Schubert Torsten; Kunze Cindy; Goris Tobias; Diekert Gabriele; Armstrong Fraser A.;
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Univ Oxford Dept Chem Inorgan Chem Lab South Parks Rd Oxford OX1 3QR Oxon England;

Univ Oxford Dept Chem Inorgan Chem Lab South Parks Rd Oxford OX1 3QR Oxon England;

Univ Jena Lehrstuhl Angew &

Okol Mikrobiol Inst Mikrobiol Philosophenweg 12 D-07743 Jena Germany;

Univ Jena Lehrstuhl Angew &

Okol Mikrobiol Inst Mikrobiol Philosophenweg 12 D-07743 Jena Germany;

Univ Jena Lehrstuhl Angew &

Okol Mikrobiol Inst Mikrobiol Philosophenweg 12 D-07743 Jena Germany;

Univ Jena Lehrstuhl Angew &

Okol Mikrobiol Inst Mikrobiol Philosophenweg 12 D-07743 Jena Germany;

Univ Oxford Dept Chem Inorgan Chem Lab South Parks Rd Oxford OX1 3QR Oxon England;

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1. Selective, light-driven enzymatic dehalogenations of organic compounds [J] . Siritanaratkul Bhavin, Islam Shams T. A., Schubert Torsten, RSC Advances . 2016,第88期

机译：有机化合物的选择性，光驱动的酶促脱卤
2. Enzymatic dehalogenation of chlorinated nitroaromatic compounds. [J] . J Thiele, R Müller, F Lingens Applied and Environmental Microbiology . 1988,第5期

机译：氯化硝基芳族化合物的酶促脱卤作用。
3. An alpha-{P2W18O62}(6-)-Based Supramolecular Hybrid Inorganic-Organic Compound with Visible Light-Driven Photocatalytic Properties [J] . Zhu Xiaofei, Yang Yu, Jiang Ni, Zeitschrift fur Anorganische und Allgemeine Chemie . 2016,第19期

机译：具有可见光驱动光催化特性的基于α-{P2W18O62}（6-）的超分子杂化无机有机化合物
4. DEHALOGENATION OF POLYHALOGENATED COMPOUNDS DISSOLVED IN ORGANIC SOLVENTS WITH THE HELP OF AOPS IN A TWO-PHASE SOLVENT-WATER SYSTEM UNDER THE INFLUENCE OF ULTRASOUND [C] . FRANTISEK KASTANEK, JIRI SOBEK, PETR KASTANEK International Conference on Environmental Science and Technology . 2011

机译：在超声波的影响下，在两相溶剂 - 水系统中的AOP中，在有机溶剂中溶解在有机溶剂中的多卤代化合物的脱氢。
5. Statistical Analysis to Identify Volatile Organic Compounds (VOCs) in Breath from Hypoglycemia and Development of Cross-Selective Nanosensors for Its Detection [D] . Daneshkhah, Ali. 2017

机译：统计分析鉴定挥发性有机化合物（VOCS）中的低血糖和交叉选择性纳米调传料的发育以进行检测
6. Enzymatic dehalogenation of chlorinated nitroaromatic compounds. [O] . J Thiele, R Müller, F Lingens 1988

机译：氯化硝基芳族化合物的酶促脱卤作用。
7. DHPA-Containing Cobalt-Based Redox Metal-Organic Cyclohelicates as Enzymatic Molecular Flasks for Light-Driven H2 Production [O] . Liang Zhao, Jian Wang, Pengyan Wu, 2017

机译：含DHPA的基于钴的氧化还原金属 - 有机环elicates作为酶分子烧瓶，用于光驱动的H2生产
8. Selective Reductions. XXI. 9-Borabicyclo(3.3.1) Nonane in Tetrahydrofuran as a New Selective Reducing Agent in Organic Synthesis. Reaction with Selected Organic Compounds Containing Representative Functional Groups. [R] . Brown, H. C., Krishnamurthy, S., Yoon, N. M. 1976

机译：选择性减少。 XXI。 9-Borabicyclo（3.3.1）四氢呋喃中的壬烷作为有机合成中的新型选择性还原剂。与含有代表性官能团的选定有机化合物反应。

Selective, light-driven enzymatic dehalogenations of organic compounds

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