Synthesis and gelation properties of poly(2-alkyl-2-oxazoline) based thermo-gels

Adam L. Fisher; Julia M. H. Schollick; Dirk G. A. L. Aarts; Martin C. Grossel

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Synthesis and gelation properties of poly(2-alkyl-2-oxazoline) based thermo-gels

机译：聚（2-烷基-2-恶唑啉）热凝胶的合成及凝胶化性能

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A series of new thermo-gelling polymers based on thermo-responsive poly(2-alkyl-2-oxazoline)s has been prepared by grafting different poly(2-alkyl-2-oxazolines) onto a polar carboxymethylcellulose backbone. Thermo-reversible gelation is observed at low concentrations (less than 5% by weight of thermo-gelling polymer). Rheology reveals that these polymers show tuneable gelation temperatures, which vary with concentration and poly(2-oxazoline) composition. This allows the gelation point to be adjusted to biologically relevant temperatures, offering a novel material with potential applications in areas such as drug delivery and tissue engineering.

机译：通过将不同的聚（2-烷基-2-恶唑啉植物嫁接到极性羧甲基纤维骨架上，制备了基于热响应聚（2-烷基-2-恶唑啉）的一系列新的热胶凝聚合物。以低浓度（小于5重量％的热胶凝聚合物）观察热可逆凝胶化。流变学揭示了这些聚合物显示可调谐凝胶化温度，其随浓度和聚（2-恶唑啉）组合物而变化。这允许将凝胶化点调节到生物相关的温度，提供一种具有潜在应用的新材料，例如药物递送和组织工程。

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《RSC Advances》 |2016年第71期|共6页
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Adam L. Fisher; Julia M. H. Schollick; Dirk G. A. L. Aarts; Martin C. Grossel;
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1. Synthesis and gelation properties of poly(2-alkyl-2-oxazoline) based thermo-gels [J] . Fisher Adam L., Schollick Julia M. H., Aarts Dirk G. A. L., RSC Advances . 2016,第71期

机译：聚（2-烷基-2-恶唑啉）热凝胶的合成及凝胶化性能
2. Mixing Poly(ethylene glycol) and Poly(2-alkyl-2-oxazoline)s Enhances Hydration and Viscoelasticity of Polymer Brushes and Determines Their Nanotribological and Antifouling Properties [J] . Morgese Giulia, Gombert Yvonne, Ramakrishna Shivaprakash N., ACS applied materials & interfaces . 2018,第48期

机译：混合聚（乙二醇）和聚（2-烷基-2-恶唑啉）S增强了聚合物刷的水合和粘弹性，并确定了纳米纤维和防污性能
3. Synthesis of Star-Shaped Polymers Based on 2-ALKYL-2-Oxazoline with a Calix[8]Arene Central Core and the Study of Their Heat-Sensitive Properties [J] . Kurlykin M. P., Bursian A. E., Dudkina M. M., Fibre Chemistry . 2015,第4期

机译：基于杯形[8]芳烃中心核的2-ALKYL-2-恶唑啉星型聚合物的合成及其热敏性能的研究
4. MODIFICATION OF GELLING KINETICS AND ELASTIC PROPERTIES BY NANO STRUCTURING OF ALGINATE GELS EXPLOITING THE PROPERTIES OF POLY-GULURONATE. [C] . K.I. Draget, O. Smidsrod Gums and Stabilisers for the Food Industry Conference . 2006

机译：纳米酸盐凝胶纳米结构改变凝胶动力学和弹性性能利用聚 - 铜酸盐的性能。
5. Synthesis of higher molecular weight poly(D-glucaramides) and poly(aldaramides) as novel gel forming agents. [D] . Smith, Tyler Nations. 2008

机译：合成更高分子量的聚（D-葡糖酰胺）和聚（醛酰胺）作为新型凝胶形成剂。
6. Co-Polymers based on Poly(14-butylene 25-furandicarboxylate) and Poly(propylene oxide) with Tuneable Thermal Properties: Synthesis and Characterization [O] . Marina Matos, Andreia F. Sousa, Patrícia V. Mendonça, 2019

机译：具有可调节热性能的基于聚（14-丁烯25-呋喃二甲酸）和聚环氧丙烷的共聚体：合成与表征
7. Synthesis and gelation properties of poly(2-alkyl-2-oxazoline) based thermo-gels [O] . Aarts, DGAL, Fisher, AL, Schollick, JMH, 2016

机译：聚（2-烷基-2-恶唑啉）基热凝胶的合成和凝胶化性质
8. Variations in the optical properties of poly(3-hexylthiophene)/C(sub 60) blends and poly(3-hexylthiophene)/sol-gel composites [R] . Wang, H. L. , Grigorva, M. , Mattes, B. R. , 1996

机译：聚（3-己基噻吩）/ C（sub 60）共混物和聚（3-己基噻吩）/溶胶 - 凝胶复合材料的光学性质的变化

Synthesis and gelation properties of poly(2-alkyl-2-oxazoline) based thermo-gels

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