β-Carboline-directed decarboxylative acylation of ortho-C(sp2)–H of the aryl ring of aryl(β-carbolin-1-yl)methanones with α-ketoacids under palladium catalysis

Shivalinga Kolle; Sanjay Batra

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β-Carboline-directed decarboxylative acylation of ortho-C(sp2)–H of the aryl ring of aryl(β-carbolin-1-yl)methanones with α-ketoacids under palladium catalysis

机译：β-咔啉 - 甲基（β-胶蛋白-1-基）甲基酮的芳基（β-胶蛋白-1-基）甲基酮的芳基环芳环芳基环羧酸甲苯的甲羧酸酰基化，α-酮酸在钯催化下

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A palladium-catalysed β-carboline directed decarboxylative acylation of ortho -C(sp ~(2) )–H of the aryl ring of aryl(β-carbolin-1-yl)methanones using α-oxocarboxylic acid as the acyl ion equivalent to form (2-aroylaryl)(β-carbolin-2-yl)methanones is described. The utility of these products for preparing β-carboline-tethered phthalazine systems is also demonstrated.

机译：一种钯催化的β-蛋白质指向芳基（β-胶蛋白-1-基）甲基酮的芳基（Sp〜（2））-H的芳基（Sp〜（2））-H使用α-氧代羧酸作为酰基离子等同于描述了形式（2-芳亚芳基）（β-胶蛋白-2-基）甲烷酮。还证明了这些用于制备β-咔啉的酞嗪系统的产品的效用。

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《RSC Advances》 |2016年第56期|共8页
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Shivalinga Kolle; Sanjay Batra;
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1. beta-Carboline-directed decarboxylative acylation of ortho-C(sp(2))-H of the aryl ring of aryl(beta-carbolin-1-yl)methanones with alpha-ketoacids under palladium catalysis [J] . Kolle Shivalinga, Batra Sanjay RSC Advances . 2016,第56期

机译：β-咔啉 - 芳基（β-碳-1-基-1-基）甲基酮的芳基（Sp（2）） - H的甲醇环的甲醇环与钯催化下的甲酮（2）） - H指导脱羧酰化酰化
2. Pd(OAc)_2-catalysed regioselective alkoxylation of aryl (β-carbolin-1-yl)methanones via β-carboline directed ortho-C(sp~2)-H activation of an aryl ring [J] . Shivalinga Kolle, Sanjay Batra Organic & biomolecular chemistry . 2015,第41期

机译：Pd（OAc）_2催化的β-咔啉定向的邻位C（sp〜2）-H芳基环活化活化芳基（β-carbolin-1-基）甲烷的区域选择性烷氧基化
3. Retraction: Palladium‐Catalyzed Decarboxylative Selective Acylation of 4H‐Benzo[d][1,3]oxazin‐4‐one Derivatives with α‐Oxo Carboxylic Acids via Preferential Cyclic Imine‐N‐Directed Aryl C?H Activation [J] . Advanced synthesis & catalysis . 2020,第3期

机译：收缩：钯 - 催化的脱羧选择性4h-苯并[1,3]的脱羧-4-一种衍生物，通过优先循环酰胺-N-指定向芳基-H激活α-氧代羧酸
4. Palladium-Catalyzed Decarboxylative Etherification of Aryl Benzyl Carbonates [C] . Hiroki Kusano, Ryoichi Kuwano Symposium on Organometallic Chemistry . 2007

机译：钯催化的碳酸芳基甲苄基乙烯基醚化
5. Mechanism of the palladium-catalyzed amination of aryl halides: Kinetic studies of the oxidative addition of aryl halides and sulfonates to phosphine complexes of Pd(0) and of the catalytic reaction of amines with aryl halides and base. [D] . Alcazar-Roman, Luis Manuel. 2001

机译：钯催化芳基卤化物胺化的机理：动力学研究氧化芳基卤化物和磺酸盐到Pd（0）的膦配合物中，以及胺与芳基卤化物和碱的催化反应。
6. Decarboxylative Palladium(II)-Catalyzed Synthesis of Aryl Amidines from Aryl Carboxylic Acids: Development and Mechanistic Investigation [O] . Jonas Rydfjord, Fredrik Svensson, Alejandro Trejos, -1

机译：脱羧钯（II）催化从芳基羧酸合成芳Am的研究和机理研究
7. Unexpected ring contraction of 1-aryl-cyclohexa-2,5-dienes under palladium catalysis [O] . Raphaël Lebeuf, Frédéric Robert, Yannick L 2014

机译：钯催化下1-芳基-环己-2,5-二烯的意外环收缩

β-Carboline-directed decarboxylative acylation of ortho-C(sp2)–H of the aryl ring of aryl(β-carbolin-1-yl)methanones with α-ketoacids under palladium catalysis

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