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A photoswitchable diarylethene heterodimer for use as a multifunctional logic gate

机译:用于多功能逻辑栅极的光学性二芳基乙烯异二聚体

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A novel multifunctional photochromic molecule, BTF–BTH , was synthesized via covalently linking two photoswitchable fluorescent diarylethenes BTFO4 and BTHTO , and the structure was characterized using NMR and MS analysis. The photophysical properties of four photoisomeric states, BTFo–BTHo , BTFc–BTHc , BTFc–BTHo and BTFo–BTHc , were studied. Interconversions among these states were readily achieved using light irradiation and the addition of Cu ~(2+) . Interestingly, a fluorescence energy transfer phenomenon was observed for BTFc–BTHc . Based on these results, logic gates, including OR, keypad lock, INHIBIT, AND, and 1:2 demultiplexer, were designed and successfully demonstrated using BTF–BTH .
机译:通过共价连接两个光学性荧光二芳基丙烯烯BTFO4和BTHTO合成新型多功能光致变色分子BTF-BTH,并且使用NMR和MS分析表征该结构。研究了四种光学态态,BTFO-BTHO,BTFC-BTHC,BTFC-BOTHO和BTFO-BTHC的光物理性质。使用光照射和加入Cu〜(2+)容易地实现这些状态中的互联。有趣的是,对于BTFC-BTHC,观察到荧光能量转移现象。基于这些结果,设计和成功地使用BTF-BTH设计了逻辑门,包括或键盘锁定,禁止和1:2解复用器。

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