Recent advances in the synthesis of benzimidazol(on)es via rearrangements of quinoxalin(on)es

Vakhid A. Mamedov

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Recent advances in the synthesis of benzimidazol(on)es via rearrangements of quinoxalin(on)es

机译：通过喹喔啉（ON）ES的重排合成苯并咪唑（ON）ES的最新进展

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This is the first review describing all the quinoxaline–benzimidazole rearrangements as a whole and the new quinoxalinone–benzimidazol(on)e rearrangements in particular when exposed to nucleophilic rearrangements for the synthesis of various biheterocyclic motifs. The scope of the rearrangements is illustrated by way of numerous examples of their application, and in doing so, the review contains over 131 references and covers all of the literature, from the first report of the rearrangement of 2,3-diphenylquinoxaline by Ogg and Bergstrom in 1931 up to more recent examples in the past few years. The mechanisms for the selected transformations are also discussed.

机译：这是第一次审查，描述了整个喹喔啉 - 苯并咪唑重排和新的喹喔啉酮 - 苯并咪唑（ON）E o o e重排，特别是当暴露于合成各种Bieheticycclic基序的亲核重排时。重排的范围是通过其应用的许多例子来说明，并且在此过程中，审查含有超过131个参考文献并涵盖所有文献，从ogg和ogg的第一个报告中的第一个报告报告到2,3-二苯基喹喔啉的重新排列伯格斯特罗姆在1931年在过去几年中最近的例子。还讨论了所选变换的机制。

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《RSC Advances》 |2016年第48期|共41页
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Vakhid A. Mamedov;
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1. Recent advances in the synthesis of benzimidazol(on)es via rearrangements of quinoxalin(on)es [J] . Mamedov Vakhid A. RSC Advances . 2016,第48期

机译：通过喹喔啉（ON）ES的重排合成苯并咪唑（ON）ES的最新进展
2. Reaction for the Synthesis of Benzimidazol-2-ones, Imidazo[5,4-b]-, and Imidazo[4,5-c]pyridin-2-ones via the Rearrangement of Quinoxalin-2-ones and Their Aza Analogues When Exposed to Enamines [J] . Vakhid A. Mamedov, Nataliya A. Zhukova, Anastasiya I. Zamaletdinova, The Journal of Organic Chemistry . 2014,第19期

机译：在暴露时，通过重新排列喹唑啉-2-苯并咪唑-2-苯并咪唑-2-苯并咪唑-2-吡啶-2-吡啶-2-吡啶-2-反应[4,5-C] - 2-吡啶-2-吡啶-2-吡啶-2-二咪唑搪瓷
3. Acid-catalyzed rearrangement of 3-(β-2-aminostyryl)quinoxalin-2(1H)ones—a new and efficient method for the synthesis of 2-benzimidazol-2-ylquinolines [J] . Vakhid A. Mamedov, Dina F. Saifina, Aidar T. Gubaidullin Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第50期

机译：酸催化的3-（β-2-氨基苯乙烯基）喹喔啉-2（1H）酮的重排—一种合成2-苯并咪唑-2-基喹啉的新方法
4. Synthesis, LC-MS analysis and preliminary investigation of some properties of novel 1,3-dihydro-2H-benzimidazol-2-one nitro and nitramino derivatives [C] . Jonas Sarlauskas, Jonita Stankeviciute, Jelena Tamuliene Seminar on New Trends in Research of Energetic Materials . 2016

机译：1,3-二氢-2H-苯并咪唑-2-酮硝基和硝基氨基衍生物的合成，LC-MS分析和某些性质的初步研究
5. I. Dearomatization of furans via [2,3]-Still-Wittig rearrangement. II. Palladium(II)- and mercury(II)-catalyzed rearrangement of substituted 1-ethynyl-2-propenyl acetates. III. Progress toward the synthesis of the terpestacin cyclopentenone core via Nazarov cyclization [D] . Caruana, Patrick Anthony 2007

机译：I.通过[2，3] -Still-Wittig重排使呋喃脱芳香化。二。钯（II）和汞（II）催化的乙酸1-乙炔基-2-丙烯基乙酸酯的重排。三，纳扎罗夫环化合成萜品碱环戊烯酮核心的进展
6. Convenient Synthesis and Anticancer Activity of Methyl2-3-(3-Phenyl-quinoxalin-2-ylsulfanyl)propanamidoalkanoatesand N-Alkyl 3-((3-Phenyl-quinoxalin-2-yl)sulfanyl)propanamides [O] . Samir M. El Rayes, Ahmed Aboelmagd, Mohamed S. Gomaa, 2019

机译：甲基的简便合成及其抗癌活性2- 3-（3-苯基-喹喔啉-2-基硫烷基）丙酰胺基链烷酸酯和N-烷基3-（（3-苯基-喹喔啉-2-基）硫烷基）丙酰胺
7. Recent advances in the synthesis of benzimidazol(on)es via rearrangements of quinoxalin(on)es [O] . Vakhid A. Mamedov 2016

机译：通过喹喔啉（ON）ES的重排合成苯并咪唑（ON）ES的最新进展

Recent advances in the synthesis of benzimidazol(on)es via rearrangements of quinoxalin(on)es

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