Construction of bimodal silsesquioxane-based porous materials from triphenylphosphine or triphenylphosphine oxide and their size-selective absorption for dye molecules

Rong Shen; Hongzhi Liu

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Construction of bimodal silsesquioxane-based porous materials from triphenylphosphine or triphenylphosphine oxide and their size-selective absorption for dye molecules

机译：从三苯基膦或三苯基膦的基于双氧化硅氧烷的多孔材料的构建及其对染料分子的尺寸选择性吸收

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Two novel hybrid porous polymers were easily prepared by the Friedel–Crafts reaction of octavinylsilsesquioxane with triphenylphosphine and triphenylphosphine oxide, respectively. They possessed unique bimodal pores with uniform micropores and mesopores centered at 1.5 nm and 3.7 nm, respectively, high surface areas up to 1105 m ~(2) g ~(?1) , high thermal stability and an excellent size-selective adsorption for dyes. These hybrid porous polymers are very promising in dye separation, water purification and treatment.

机译：通过八戊酰基硅基硅氧烷与三苯基膦和三苯基膦氧化物的Friedel-Crafts反应，容易制备两种新型杂化多孔聚合物。它们具有独特的双峰孔，分别以1.5nm和3.7nm为中心的均匀微观孔，高表面积高达1105 m〜（2）g〜（α1），高热稳定性和染料的优异尺寸选择性吸附性。这些杂种多孔聚合物在染料分离，水净化和处理中非常有前途。

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《RSC Advances》 |2016年第44期|共9页
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Rong Shen; Hongzhi Liu;
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1. Construction of bimodal silsesquioxane-based porous materials from triphenylphosphine or triphenylphosphine oxide and their size-selective absorption for dye molecules [J] . Shen Rong, Liu Hongzhi RSC Advances . 2016,第44期

机译：由三苯基膦或三苯基膦氧化物构建双峰倍半硅氧烷基多孔材料及其对染料分子的尺寸选择性吸收
2. A Practical One-Pot Transformation of Triphenylphosphine Oxide to Triphenylphosphine by Reduction of in situ Generated Triphenylphosphine Dichloride [J] . Yano T, Hoshino M, Kuroboshi M, Synlett . 2010,第5期

机译：通过还原原位生成的三苯基膦二氯化物将三苯基膦氧化物实际一锅转化为三苯基膦
3. Measurement of Peroxide Values in Oils by Triphenylphosphine/Triphenylphosphine Oxide (TPP/TPPO) Assay Coupled with FTIR-ATR Spectroscopy: Comparison with Iodometric Titration [J] . Deyrieux Charlotte, Villeneuve Pierre, Barea Bruno, European Journal of Lipid Science and Technology . 2018,第8期

机译：通过三苯基膦/三苯基膦（TPP / TPPO）测定与FTIR-ATR光谱偶联的过氧化物值的测量：与碘滴定的比较
4. Crystal growth of triphenylphosphine oxide 4-nitrophenol (TP4N) for nonlinear optical (NLO) applications [C] . Muthu Senthil Pandian, P. Karuppasamy, T. Kamalesh, DAE Solid State Physics Symposium . 2018

机译：非线性光学（NLO）应用的三苯基膦氧化物4-硝基苯酚（TP4N）的晶体生长
5. Kinetics and mechanisms of the ligand substitution reactions of cyclopentadienyl M tetracarbonyl, indenyl M tetracarbonyl, M = niobium or tantalum, and molybdenum(2) (carbon monoxide)(6) [mu-eta(5),eta(5)-cyclopentadienylide-carbon alkyl(2)-cyclopentadienylide] with tributylphosphine, triphenylphosphine and triphenylphosphite. Photo-assisted carbonylation of supercritical ethane, ethane and methane in supercritical carbon dioxide by trans-chlorocarbonylbis(trimethylphosphine)rhodium(I). [D] . Lukmanova-Kline, Dinara Maratovna. 2001

机译：动力学和机制的环戊二烯基M四羰基，茚基M四羰基，M =铌或钽和钼（2）（一氧化碳）（6）[mu-eta（5），eta（5）-cyclopentadienylide-碳烷基（2）-环戊二烯基]与三丁基膦，三苯基膦和亚磷酸三苯酯。通过反氯羰基双（三甲基膦）铑（I）在超临界二氧化碳中对超临界乙烷，乙烷和甲烷进行光辅助羰基化。
6. Triphenylphosphine-based functional porous polymer as an efficient heterogeneous catalyst for the synthesis of cyclic carbonates from CO2 [O] . Siduo Wu, Chao Teng, Sheng Cai, 2017

机译：基于三苯膦的功能性多孔聚合物可作为有效的非均相催化剂用于由CO2合成环状碳酸酯
7. Studies on Complexes of Metal(II) Carboxylates with Donor Molecules. IV. Complexes of Nickel(II) Chloroacetates with PyridineN-Oxides and Triphenylphosphine Oxide [O] . Narsingh Kumar, Piyara Lal Kachroo, Rama Kant 1980

机译：用供体分子的金属（II）羧酸盐复合物的研究。 IV。镍（II）氯乙酸酯与吡啶氧化物和三苯基膦酰胺的复合物
8. Initial Submission: Letter from Atochem North America Inc. to USEPA re: Toxicity Studies of Triphenylphosphine and Triphenyl-Phosphine Oxide with Attachments and Cover Letter dated 10/22/1992 [R] . 1992

机译：初始提交：atochem North america Inc.致UsEpa的信：re：三苯基膦和三苯基氧化膦的毒性研究及附件和求职信日期为1992年10月22日

Construction of bimodal silsesquioxane-based porous materials from triphenylphosphine or triphenylphosphine oxide and their size-selective absorption for dye molecules

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