Synthesis and characterization of N-heterocyclic carbene-palladium(ii) chlorides-1-methylindazole and -1-methylpyrazole complexes and their catalytic activity toward C–N coupling of aryl chlorides

Xiao-Yun Zhao; Quan Zhou; Jian-Mei Lu

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Synthesis and characterization of N-heterocyclic carbene-palladium(ii) chlorides-1-methylindazole and -1-methylpyrazole complexes and their catalytic activity toward C–N coupling of aryl chlorides

机译：N-杂环 - 钯（II）氯化物-1-甲基丙醇和-1-甲基吡唑络合物的合成与表征及其氨基氯C-N偶联的催化活性

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A series of N -heterocyclic carbene-palladium( II ) chlorides-1-methylindazole and -1-methylpyrazole complexes was successfully synthesized and fully characterized by X-ray single crystal diffraction. In addition, initial investigations of their catalytic activity showed that they were efficient catalysts in the C–N coupling of primary and secondary amines with aryl chlorides at low catalyst loadings.

机译：成功合成了一系列N-丙炔菌 - 钯（II）氯化物-1-甲基吲唑和-1-甲基吡唑复合物，并通过X射线单晶衍射充分表征。此外，其催化活性的初步研究表明，它们在低催化剂载量下用芳基氯化物的仲胺和仲胺的C-N偶联中是有效的催化剂。

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《RSC Advances》 |2016年第29期|共7页
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Xiao-Yun Zhao; Quan Zhou; Jian-Mei Lu;
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1. Synthesis and characterization of N-heterocyclic carbene-palladium(II) chlorides-1-methylindazole and-1-methylpyrazole complexes and their catalytic activity toward C-N coupling of aryl chlorides [J] . Zhao Xiao-Yun, Zhou Quan, Lu Jian-Mei RSC Advances . 2016,第29期

机译：N-杂环 - 钯（II）氯化物-1-甲基吲唑和1-甲基吡唑络合物的合成与表征及其氨基氯C-N偶联的催化活性
2. Supporting ligand-assisted N-heterocyclic carbene palladium complexes: characterization, computation, and catalytic activity in Suzuki-Miyaura cross coupling between aryl and heteroaromatic chlorides and various boronic acids [J] . Shen An, Hu Yu-Cai, Liu Ting-Ting, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第19期

机译：支持配体辅助的N-杂环卡宾钯配合物：芳烃和杂芳族氯化物与各种硼酸之间的Suzuki-Miyaura交叉偶联的表征，计算和催化活性
3. N-Heterocyclic Carbene-Palladium Complexes [(NHC)Pd-(acac)Cl]: Improved Synthesis and Catalytic Activity in Large-Scale Cross-Coupling Reactions [J] . Nicolas Marion, Pierre de Fremont, Iris M. Puijk Advanced synthesis & catalysis . 2007,第14a15期

机译：N-杂环碳-钯配合物[（NHC）Pd-（acac）Cl]：大规模交叉偶联反应中合成和催化活性的改进
4. Immobilized Cu (II)—Amino Acid Complexes asProspective Highly Efficient Catalytic Materials:Synthesis, Structural Characterization andCatalytic Activities [C] . Istvan Palinko, Adrien Ordasi, Janos T. Kiss, International Conference on Perspectives in Vibrational Spectroscopy . 2008

机译：固定化Cu（II） - 氨基酸复合物表现出高效催化材料：合成，结构表征和催化活性
5. Part I: Microwave-Assisted Continuous Flow Organic Synthesis (MACOS) and the Heck-type aminocarbonylation of aryl halides, and, the Suzuki-Miyaura cross-coupling of chloroformates. Part II: Structure-activity relationship (SAR) analysis of NHC-palladium PEPPSI complexes in aminations and cross-couplings [D] . Nasielski, Joanna 2009

机译：第一部分：微波辅助连续流动有机合成（MACOS）和芳基卤化物的Heck型氨基羰基化，以及氯甲酸酯的Suzuki-Miyaura交叉偶联。第二部分：胺和交叉偶联中NHC-钯PEPPSI复合物的结构-活性关系（SAR）分析
6. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis Characterization and Reactivity [O] . Deidra L. Gerlach, Sopheavy Siek, Dalton B. Burks, -1

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7. Synthesis of novel N-heterocyclic carbene-palladium complexes and their catalytic activity [O] . Guest Daniel P 2017

机译：新型N-杂环卡宾 - 钯配合物的合成及其催化活性
8. Synthesis, Characterization and Properties of Stable Chromium (III) Aryl Isocyanide Complexes [R] . Bohling, D. A., Mann, K. R. 1983

机译：稳定的铬（III）芳基异氰化物配合物的合成，表征及性质

Synthesis and characterization of N-heterocyclic carbene-palladium(ii) chlorides-1-methylindazole and -1-methylpyrazole complexes and their catalytic activity toward C–N coupling of aryl chlorides

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