Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones

Alessandro Palmieri; Serena Gabrielli; Susanna Sampaolesi; Roberto Ballini

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Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones

机译：Nitroaldol（Henry）2-氧氧醛与硝基烷烃的反应作为1,2-Diketone的有用，一锅合成的战略步骤

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The nitroaldol (Henry) reaction of 2-oxoaldehydes with a variety of nitroalkanes, under basic heterogeneous conditions and microwave irradiation, affords 1,2-diketones in a one-pot way. The key step of the process involves the nitrous acid elimination from the nitroalkanol intermediates instead of the standard water elimination.

机译：在碱性异质条件下，2-氧氧醛（HENRALDOL（HENRALDOL）的2-氧氧醛的反应，在碱性异质条件下，微波辐射提供1,2-二酮，以单壶方式提供1,2-二酮。该方法的关键步骤涉及来自硝基烷醇中间体的亚硝酸而不是标准的水消除。

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《RSC Advances》 |2015年第46期|共4页
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Alessandro Palmieri; Serena Gabrielli; Susanna Sampaolesi; Roberto Ballini;
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1. Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones [J] . Palmieri Alessandro, Gabrielli Serena, Sampaolesi Susanna, RSC Advances . 2015,第46期

机译：2-氧醛与硝基烷的硝基醛（亨利）反应作为有效的一锅合成1,2-二酮的战略步骤
2. A New Heterogeneous One-Pot Process for Both Nitroaldol (Henry) and Michael Reactions from Primary Haloalkanes via Nitroalkanes [J] . Roberto Ballini, Luciano Barboni, Alessandro Palmieri Synlett . 2007,第19期

机译：硝基卤烷通过硝基烷进行硝基醛（亨利）和迈克尔反应的新型异构一锅法
3. Nitroalkenes as Latent 1,2-Biselectrophiles - A Multicatalytic Approach for the Synthesis of 1,4-Diketones and Their Application in a Four-Step One-Pot Reaction to Polysubstituted Pyrroles [J] . Fuchs Patrick J. W., Zeitler Kirsten The Journal of Organic Chemistry . 2017,第15期

机译：Nitroalkenes作为潜在的1,2-双路电针 - 一种为1,4-二酮合成的多浅型方法及其在四步单罐反应中的三泊型胃肠杆菌中的应用
4. SYNTHESIS OF 2-(2'-PIPERIDNYL)PYRIDINE DERIVATIVES AND THEIR USE AS LIGANDS IN ASYMMETRIC HENRY AND AZA-HENRY REACTIONS [C] . Artur Noole, Tonis Kanger European Symposium on Organic Chemistry . 2009

机译：合成2-（2'-哌啶基）吡啶衍生物及其用作不对称亨利和AZA-HENRY反应中的配体的用途
5. Umpolung Amide Synthesis Mechanistic Studies, Development of a New N-Aryl Amide Synthesis, and α-Oxy- and α-Thio-Nitroalkanes in the Bam-Catalyzed Aza-Henry Reaction [D] . Crocker, Michael. 2021

机译：umpolung酰胺合成机械研究，在Bam催化的Aza-henry反应中开发新的N-芳基合成，α-氧 - 和α-硫代 - 硝基烷烃
6. Keratin Protein-Catalyzed Nitroaldol (Henry) Reaction and Comparison with Other Biopolymers [O] . Marleen Häring, Asja Pettignano, Françoise Quignard, 2016

机译：角蛋白催化的硝基醛醇（亨利）反应及与其他生物聚合物的比较
7. Nitroaldol (Henry) reaction of 2-oxoaldehydes with\ud nitroalkanes as a strategic step for a useful, one-pot\ud synthesis of 1,2-diketones [O] . A. Palmieri, S. Gabrielli, S. Sampaolesi, 2015

机译：2-氧醛与\ ud的硝基醛（亨利）反应硝基烷作为有用的一锅法产品的战略步骤 1,2-二酮的合成

Nitroaldol (Henry) reaction of 2-oxoaldehydes with nitroalkanes as a strategic step for a useful, one-pot synthesis of 1,2-diketones

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