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Highly efficient WO3–ZnO mixed oxides for photocatalysis

机译:高效的WO3-ZnO混合氧化物用于光催化

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Monoclinic nanocuboid WO _(3) enhanced the photocatalyst efficiency of quasi nanobelt zinc oxide for dye degradation in the presence of visible light radiation. Combustion synthesized ZnO resulted in a belt-like morphology through in situ cluster formation of near spherical particles but homogenously disperses and strongly adheres to nanocuboid WO _(3) during physical mixing. Cationic methylene blue (MB) and anionic orange G (OG) undergo degradation through a charge transfer mechanism in the presence of WO _(3) –ZnO (1?:?9 weight percentage ratio) mixture. The photocatalytic reaction was enhanced due to the reduction in the recombination of photogenerated electron–holes. The high degree of 90% degradation of both dyes is due to the activity of the mixed oxides, which is much higher than that obtained either with WO _(3) or ZnO individually.
机译:单斜纳米吡吡吡吡吡吡吡吡吡吡吡吡吡盖WO _(3)增强了在可见光辐射存在下染料降解染料的乙酰氧化物的光催化剂效率。燃烧合成的ZnO通过原位簇形成近球形颗粒而产生的带状形态,但在物理混合过程中均匀地分散并强烈地粘附到纳米吡吡吡替纳米_(3)。阳离子亚甲基蓝(Mb)和阴离子橙g(og)通过电荷转移机制在WO _(3)-ZnO(1?:9重量百分比比率)混合物存在下通过电荷转移机制进行降解。由于光发性电子 - 孔的重组还原,增强了光催化反应。两种染料的高度为90%的降解是由于混合氧化物的活性,其远高于单独用WO _(3)或ZnO获得的活性。

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