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Third-generation solar cells: a review and comparison of polymer:fullerene, hybrid polymer and perovskite solar cells

机译:第三代太阳能电池:聚合物:富勒烯,杂种聚合物和钙钛矿太阳能电池的综述及比较

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The need for large scale low carbon solar electricity production has become increasingly urgent for reasons of energy security and climate change mitigation. Third-generation solar cells (SCs) are solution processed SCs based on semiconducting organic macromolecules, inorganic nanoparticles or hybrids. This review considers and compares three types of promising 3rd-generation SCs: polymer:fullerene, hybrid polymer and perovskite SCs. The review considers work reported since an earlier review (Saunders et al. , Adv. Colloid Interface Sci. , 2008, 138 , 1) and highlights the great progress that has been made in each area. We consider the operation principles for each SC type and also review the state-of-the-art devices. The polymer:fullerene and hybrid polymer SC open circuit voltages are compared to values predicted from the well-known Scharber equation and similarities and differences discussed. The perovskite SCs are also considered and their remarkable rate of power conversion efficiency performance increase is discussed. The review considers the requirements for large-scale deployment in the contexts of semiconducting polymer and hole transport matrix synthesis and materials selection. It is concluded that the 3rd-generation SC technologies discussed here are well placed for major contribution to large scale energy production. (This has already been partially demonstrated for polymer:fullerene SCs.) Looking further ahead we propose that several of the 3rd-generation SCs considered here have excellent potential to provide the low cost large-scale deployment needed to meet the terawatt challenge for solar electricity generation.
机译:由于能源安全和气候变化缓解,对大规模低碳太阳能电力生产的需求变得越来越紧迫。第三代太阳能电池(SCS)是基于半导体有机大分子,无机纳米粒子或杂种的溶液SCS。本综述考虑并比较了三种有前途的第3次生成SCS:聚合物:富勒烯,杂种聚合物和钙钛矿SC。审查考虑了自早期审查以来报告的工作(Saunders等,ADV。胶体接口SCI。,2008,138,1)并突出了每个区域所取得的巨大进展。我们考虑每个SC类型的操作原理,也审查最先进的设备。聚合物:将富勒烯和混合聚合物SC开路电压与从众所周知的Scharber方程预测的值进行比较,并且讨论的相似性和差异。还考虑了Perovskite SCS,并讨论了它们显着的功率转换效率性能增加率。该审查考虑了在半导体聚合物和空穴传输基质合成和材料选择的上下文中进行大规模部署的要求。结论是,这里讨论的第三代SC技术良好地为大规模能源生产的主要贡献提供了良好的贡献。 (这已被部分展示用于聚合物:富勒烯SCS。)寻找进一步的领先我们提出,这里考虑的几个第三代SCS具有优异的潜力,可以提供满足太阳能电力的Terawatt挑战所需的低成本大规模部署一代。

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