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Quantification of colour stimuli through the calculation of CIE chromaticity coordinates and luminance data for application to in situ colorimetry studies of electrochromic materials

机译:通过计算CIE色度坐标和亮度数据来量化颜色刺激,用于电致变色材料的原位比色研究

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摘要

The development of a Microsoft~® Excel~®spreadsheet is described, for the accurate calculation of CIE (Commission Internationale de l'Eclairage) 1931 xy chromaticity coordinates and luminance data from visible region absorption spectra recorded in transmission mode. Using firmly established CIE principles, absor-bance-wavelength data from visible spectra recorded using a Hewlett Packard 8452A diode array spec-trophotometer are taken as input, with chromaticity coordinates being generated as output. The colorimetric transformations described are well known to colour scientists, with the methodology and background now being made accessible to the electrochromic materials community. Colour stimulus measurement example calculation results are firstly presented for aqueous solutions of the dyes, Eryth-rosin B (red), Acid Green 25 and Remaxol Brilliant Blue R, and then for tracking electrochromic in situ colour stimulus changes in the methyl viologen and n-heptyl viologen systems. The quantification of colour during each viologen dication to cation radical reduction process, and each reverse (oxidation) process, showed that subtle changes in both hue and luminance could be detected, with evidence of colour contributions from both the cation radical and the cation radical dimer.
机译:描述了Microsoft®Excel®电子表格的开发,用于精确计算CIE(国际照明委员会)1931 xy色度坐标和来自以透射模式记录的可见区域吸收光谱的亮度数据。使用牢固建立的CIE原理,将使用Hewlett Packard 8452A二极管阵列分光光度计记录的可见光谱中的吸收峰波长数据作为输入,并生成色度坐标作为输出。所描述的比色转换是色彩科学家所熟知的,电致变色材料社区现在可以使用该方法和背景。首先给出了染料水溶液,Eryth-rosin B(红色),Acid Green 25和Remaxol Brilliant Blue R的颜色刺激测量示例计算结果,然后用于跟踪甲基紫精和n-染料的电致变色原位颜色刺激变化。庚基紫精体系。每种紫精对阳离子自由基还原过程以及每个逆向(氧化)过程中颜色的定量显示,可以检测到色调和亮度的细微变化,并证明了阳离子自由基和阳离子自由基二聚体对颜色的贡献。

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