CATALYTIC CONVERSION OF CARBON DIOXIDE USING PHASE TRANSFER CATALYSTS

D. W. PARK; J. Y. MOON; J. G. YANG

首页> 外文期刊>Energy Conversion & Management >CATALYTIC CONVERSION OF CARBON DIOXIDE USING PHASE TRANSFER CATALYSTS

【24h】

CATALYTIC CONVERSION OF CARBON DIOXIDE USING PHASE TRANSFER CATALYSTS

机译：相转移催化剂催化二氧化碳的转化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

In the present study, synthesis of 5-membered cyclic carbonates from CO_2 and epoxides, such as glycidyl methacrylate(GMA) and diglycidyl 1,2-cyciohexane dicarboxylate(DCD), were investigated in view of the characteristics of phase transfer catalysts, reaction mechanisms and kinetics. Quaternary salts showed a good conversion of epoxide at latm of CO_2 pressure. Among the salts tested, the one having a larger alkyl group and a more nucleophilic counter anion exhibited a better catalytic activity. Kinetic studies in a semi-batch reactor, through which a slow stream of CO_2 is continuously passed, showed that the reaction rate was pseudo-first order with respect to the concentration of epoxide.

机译：鉴于相转移催化剂的特性，反应机理，本研究从CO_2和环氧化物，如甲基丙烯酸缩水甘油酯（GMA）和1,2-环己基二羧酸二缩水甘油酯（DCD）合成了五元环状碳酸酯。和动力学。季盐在CO_2压力下显示出良好的环氧转化率。在所测试的盐中，具有更大烷基和更亲核抗衡阴离子的盐表现出更好的催化活性。在半间歇式反应器中进行的动力学研究表明，缓慢的CO_2流连续通过该反应器，相对于环氧化物的浓度，反应速率是伪一级。

著录项

来源
《Energy Conversion & Management》 |1997年第suppla期|p.449-454|共6页
作者
D. W. PARK; J. Y. MOON; J. G. YANG;
展开▼
作者单位

展开▼
收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类能源与动力工程;
关键词
Carbon dioxide; catalytic conversion; kinetics;

机译：二氧化碳催化转化动力学;

相似文献

外文文献
中文文献
专利

1. Catalytic Conversion of Carbon Dioxide to Methane on Ruthenium-Cobalt Bimetallic Nanocatalysts and Correlation between Surface Chemistry of Catalysts under Reaction Conditions and Catalytic Performances... [J] . The Catalyst Review Newsletter Group The Catalyst Review Newsletter . 2012,第11期

机译：钌-钴双金属纳米催化剂上二氧化碳到甲烷的催化转化以及反应条件下催化剂表面化学性质与催化性能的关系...
2. Photo-thermal synergistically catalytic conversion of glycerol and carbon dioxide to glycerol carbonate over Au/ZnWO4-ZnO catalysts [J] . Liu Jiaxiong, Li Yajin, Liu Huimin, Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2019,第期

机译：甘油和二氧化碳对Au / ZnWO4-ZnO催化剂的光热协同催化转化甘油和二氧化碳
3. Mn-based MOFs as efficient catalysts for catalytic conversion of carbon dioxide into cyclic carbonates and DFT studies [J] . Wu Yuanfeng, Song Xianghai, Zhang Jiahui, Chemical Engineering Science . 2019,第期

机译：基于MN的MOF作为用于催化转化二氧化碳至环碳酸酯和DFT研究的高效催化剂
4. LIQUID-PHASE CATALYTIC TRANSFER HYDROGENATION OF AROMATIC NITRO COMPOUNDS OVER NICKEL-DOPED CARBON CATALYSTS [C] . Li Xing, Jieshan Qiu, Yangying Chen, International Carbon Conference(Carbon 2007); 20070715-20; Seattle,WA(US) . 2007

机译：镍掺杂碳催化剂上芳族硝基化合物的液相催化转移加氢
5. Catalytic Conversion of Carbon Monoxide and Methane over Metal and Metal Oxide Catalysts: Synthesis, In-Situ X-Ray Spectroscopy Study, and Catalytic Performance [D] . Liu, Wenchi. 2018

机译：金属和金属氧化物催化剂中一氧化碳和甲烷的催化转化：合成，原位X射线光谱研究，催化性能
6. Catalytic conversion of carbon dioxide into dimethyl carbonate using reduced copper-cerium oxide catalysts as low as 353 K and 1.3 MPa and the reaction mechanism [O] . Seiki Wada, Kazuki Oka, Kentaro Watanabe, 2013

机译：使用还原型铜-铈氧化物催化剂低至353 K和1.3 MPa将二氧化碳催化转化为碳酸二甲酯及其反应机理
7. Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Promoted Rhodium Catalysts. I. The Effect of Additives on Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Silica Supported Rhodium Catalysts. [O] . Hitoshi KUSAMA, Kazuhiro SAYAMA, Kiyomi OKABE, 1995

机译：通过促进铑催化剂的二氧化碳催化氢化乙醇合成。 I.二氧化硅上二氧化碳催化氢化添加剂对乙醇合成的作用。

CATALYTIC CONVERSION OF CARBON DIOXIDE USING PHASE TRANSFER CATALYSTS

摘要

著录项

相似文献

相关主题

期刊订阅