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Temperature dependences of the soret coefficient and of the thermo- diffusion coefficient of polymers from thermal field-flow fractionaltion data

机译:根据热场流分馏数据,聚合物的soret系数和热扩散系数与温度的关系

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摘要

Thermal field-flow fractionation (thermal FFF) separates efficiently and rapidly polymers and colloidal materials according to their Soret coefficient. A retention model, allowing the thermal conductivity And viscosity of the carrier liquid as well as the Soret Coefficient of the polymer to be dependent of the Temperature has been developed. This model is used To determine the temperature of the Soret coefficient Of polystyrenes in ethylbenzene from experimental Retention data of polymer standards obtained at Various cold wall temperatures. It is found that the Thermodiffusion coefficient increases with increasing Temperatures.
机译:热场流分馏(thermal FFF)根据其Soret系数快速有效地分离聚合物和胶体材料。已经开发了一种保留模型,该模型允许载液的导热率和粘度以及聚合物的Soret系数取决于温度。该模型用于根据在各种冷壁温度下获得的聚合物标准品的实验保留数据确定乙苯中聚苯乙烯的Soret系数的温度。已经发现,热扩散系数随着温度的升高而增加。

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