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Biomonitoring Of Metal Deposition In The Vicnity Of Eregli Steel Plant In Turkey

机译:土耳其Eregli钢铁厂附近金属沉积物的生物监测

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This article describes the first attempt to study the concentration of seven element (Fe, Pb, Ni, Cr, Cu, Co, and As) contaminations in the vicinity of the Eregli Iron and Steel Plant (ERDEMIR) by analysis of two pleurocarpic moss species (Hypnum cupressiforme and Scleropodium purum). Samples of H. cupressiforme were collected from May 2003 to October 2004. Unwashed, dried samples were digested with HNO_3/HClO_4, and the concentrations of heavy metals were determined by graphite-furnace atomic absorption spectrometry (GFAAS). In the region, general orders of heavy metal content in samples of mosses were determined as follows: Fe>Pb>Cr>Ni>Cu>Co> As. Comparisons were made between the two moss species for those elements presents at different concentrations and regression analysis were made to see interspecies relationship. H. cupressiforme and S. purum are significantly correlated for only Fe (P < 0.01) having Pearson's correlation coefficient as 0.93, indicating interspecies calibration for Fe. The ratios (Hc/Sp) were relatively better correlated with 1/Sp for As than for other metals, suggesting a saturation effect in H. cupressiforme for As. The deposition of metals due to the operation of the steel plant has been established and could be further monitored. Such information could be useful for forensic studies aiming to apportion between different possible sources of those metals.
机译:本文介绍了通过分析两种胸膜藓类物种来研究埃雷利钢铁厂(ERDEMIR)附近七种元素(铁,铅,镍,铬,铜,钴和砷)的浓度的首次尝试。 (Hypnum cupressiforme和Scleropodium purum)。从2003年5月至2004年10月收集杯形杆菌的样品。未经洗涤的干燥样品用HNO_3 / HClO_4消解,并通过石墨炉原子吸收光谱法(GFAAS)测定重金属的浓度。在该地区,苔藓样品中重金属含量的一般顺序确定如下:Fe> Pb> Cr> Ni> Cu> Co> As。比较了两种苔藓物种在不同浓度下存在的那些元素,并进行了回归分析以了解种间关系。 H.cupressiforme和S.purum仅与Pearson相关系数为0.93的Fe显着相关(P <0.01),表明种间标定了Fe。 As的比值(Hc / Sp)与1 / Sp的相关性相对于其他金属更好,表明在H.cupressiforme中As的饱和效应。已经确定了由于钢铁厂的运营而导致的金属沉积,并且可以对其进行进一步监控。这样的信息对于法医研究可能是有用的,这些研究旨在对这些金属的不同可能来源进行分摊。

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