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Provenance and bioaccessibility of rare earth elements in atmospheric particles in areas impacted by the optoelectronic industry

机译:稀土元素在光电工业影响的区域中稀土元素的出差和生物可接为性

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摘要

Rare earth elements (REEs) are widely used in optoelectronic industries, and they can be emitted into the environment and may induce biological effects. In this study, we investigated the provenance and bio-accessibility of REEs in atmospheric particles (APs) collected from areas impacted by the optoelectronic industry. The geoaccumulation index (I-geo) values showed that Y, Eu, and Tb were much more enriched in the APs from the optoelectronic recycling sites than in those from the optoelectronic producing sites and were not enriched in the APs from the optoelectronic administrative sites and background sites. The characteristic parameters and the distribution patterns of REEs demonstrated that the AP samples from the recycling sites and producing sites showed remarkably positive Eu and Tb anomalies. According to the positive matrix factorization (PMF) model, the optoelectronic industry was quantitatively determined to contribute 82.8% of Y, 86.5% of Eu, and 83.4% of Tb. Furthermore, an in vitro physiologically based extraction test (PBET) was performed to assess the bioaccessibility of REEs in the APs. The results showed that the bioaccessibility of all the REEs in the APs was below 50.0% in the human gastrointestinal tract, with higher values in the gastric phases than in the intestinal phases. In particular, extremely low gastric bioaccessibilities of Tb and Ce and relatively high gastric bioaccessibilities of Y and Eu were observed in the APs from the recycling sites and producing sites, which may due to the chemical composition of the compounds containing REEs that are used in the optoelectronic industry. In conclusion, our results provide additional information about the contribution and influence of the optoelectronic industry on the provenance and bioaccessibility of REEs in APs. (c) 2020 Elsevier Ltd. All rights reserved.
机译:稀土元素(REES)广泛用于光电行业,它们可以发射到环境中,并可能诱导生物学效应。在这项研究中,我们调查了从由光电工业影响的区域收集的大气颗粒(AP)中REES的出处和生物可接触。地质分解指数(I-Geo)值显示Y,Eu和Tb从光电回收位点的AP中富集,而不是来自光电子生产位点的AP,并且在光电行政场所的AP中未富集APS和背景网站。 Rees的特征参数和分布模式证明,来自回收位点和产生位点的AP样品显示出显着的欧盟和Tb异常。根据正矩阵分解(PMF)模型,定量测定光电工业以贡献82.8%的欧,86.5%的欧盟,83.4%的TB。此外,进行体外的生理学提取试验(PBET)以评估APS中REES的生物可接受性。结果表明,人胃肠道的所有REES的生物可接受性低于50.0%,胃相的值较高,比在肠阶段中。特别地,在回收位点的APS中观察到Tb和Ce的Tb和Ce的胃生物生物和y和欧盟的相对高的胃生物侵蚀性,这可能是由于含有在中使用的复合物的化合物的化学成分光电工业。总之,我们的结果提供了有关光电行业对APS中REES的出处和生物可接受的贡献和影响的额外信息。 (c)2020 elestvier有限公司保留所有权利。

著录项

  • 来源
    《Environmental Pollution》 |2020年第1期|114349.1-114349.8|共8页
  • 作者单位

    Huaqiao Univ Dept Environm Sci & Engn Xiamen 361021 Fujian Peoples R China;

    Chinese Acad Sci Inst Urban Environm Key Lab Urban Environm & Hlth Xiamen 361021 Fujian Peoples R China|Univ Chinese Acad Sci Beijing 100049 Peoples R China;

    Huaqiao Univ Dept Environm Sci & Engn Xiamen 361021 Fujian Peoples R China;

    Huaqiao Univ Dept Environm Sci & Engn Xiamen 361021 Fujian Peoples R China;

    Huaqiao Univ Dept Environm Sci & Engn Xiamen 361021 Fujian Peoples R China;

    Xiamen Huaxia Univ Dept Sci & Technol Inspect Xiamen 361024 Fujian Peoples R China;

    Xiamen Huaxia Univ Dept Sci & Technol Inspect Xiamen 361024 Fujian Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Rare earth elements; Optoelectronic industry; Atmospheric particle; PMF; Bioaccessibility;

    机译:稀土元素;光电工业;大气粒子;PMF;生物可接近性;

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