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Widespread Occurrence of Bisphenol A in Daily Clothes and Its High Exposure Risk in Humans

机译:双酚A在日常服装中的广泛分布及其在人体中的高暴露风险

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摘要

Bisphenol A (BPA) is an important endocrine disrupting chemical. Although high levels of BPA in some new clothes have been reported, the occurrence of bisphenol chemicals including BPA in daily clothes is still unknown, and the human exposure to BPA in clothes has not been well assessed. In this study, used/washed clothes were collected from residents' wardrobes and the concentrations of BPA and its analogues were detected. BPA was present in all the used clothes at concentrations ranging from 3.30 to 471 ng/g (median: 34.2 ng/g; mean +/- SD: 57.5 +/- 93.6 ng/g), while bisphenol S was also detected in 29% of the samples. Although higher average concentration (88.4 +/- 289 ng/g) and maximum concentration (1823 ng/g) of BPA were found in the new clothes, the median concentration of BPA in the used clothes (34.2 ng/g) was even higher than that in the new clothes (17.7 ng/g). Cross contamination of BPA during laundering was identified by a simulated laundry experiment, which explained the homogenizing tendency of bisphenol contaminants in the used clothes. An estimated dermal exposure dose of 52.1 ng/kg BW/d was obtained for BPA exposure in children from the highly polluted sweaty clothes (with BPA concentration of 199 ng/g). This indicates a relatively high exposure risk in humans. Compared to other exposure routes, the contribution of dermal exposure dose of BPA from the daily clothes should not be neglected.
机译:双酚A(BPA)是一种重要的内分泌干扰化学物质。尽管已经报道了一些新衣服中的双酚A含量很高,但仍不清楚在日常服装中是否存在双酚类化学物质,包括双酚A,而且人体对双酚A的暴露程度尚未得到充分评估。在这项研究中,从居民的衣橱中收集了用过的/洗过的衣服,并检测了BPA及其类似物的浓度。所有使用过的衣服中的BPA浓度均在<3.30至471 ng / g(中位数:34.2 ng / g;平均值+/- SD:57.5 +/- 93.6 ng / g)之间,而双酚S在29%的样本。尽管在新衣服中发现了较高的BPA平均浓度(88.4 +/- 289 ng / g)和最大浓度(1823 ng / g),但旧衣服中的BPA中位数浓度更高(34.2 ng / g)比新衣服要高(17.7 ng / g)。通过模拟洗衣实验确定了洗衣过程中BPA的交叉污染,这说明了用过的衣服中双酚类污染物的均质化趋势。从高污染的汗湿衣服(BPA浓度为199 ng / g)的儿童中,双酚A的暴露量估计为52.1 ng / kg BW / d。这表明人类的暴露风险相对较高。与其他暴露途径相比,日常服务中BPA皮肤暴露剂量的贡献不可忽略。

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  • 来源
    《Environmental Science & Technology》 |2019年第12期|7095-7102|共8页
  • 作者单位

    Nankai Univ, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin Key Lab Environm Technol Complex Trans Me, Tianjin 300071, Peoples R China;

    Nankai Univ, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin Key Lab Environm Technol Complex Trans Me, Tianjin 300071, Peoples R China;

    Nankai Univ, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin Key Lab Environm Technol Complex Trans Me, Tianjin 300071, Peoples R China;

    Nankai Univ, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin Key Lab Environm Technol Complex Trans Me, Tianjin 300071, Peoples R China;

    Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China;

    Nankai Univ, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin Key Lab Environm Technol Complex Trans Me, Tianjin 300071, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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