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首页> 外文期刊>Environmental Science & Technology >Beyond Traditional Organophosphate Triesters: Prevalence of Emerging Organophosphate Triesters and Organophosphate Diesters in Indoor Dust from a Mega E-waste Recycling Industrial Park in South China
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Beyond Traditional Organophosphate Triesters: Prevalence of Emerging Organophosphate Triesters and Organophosphate Diesters in Indoor Dust from a Mega E-waste Recycling Industrial Park in South China

机译:除了传统的有机磷酸酯的历史:来自华南地区的Mega E废弃的工业园区的室内灰泥的新兴有机磷酸酯和有机磷酸二酯的患病率

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摘要

Numerous studies have reported the environmental contamination with traditional organophosphate triesters (tri-OPEs), but there is very little information on emerging tri-OPEs and organophosphate diesters (di-OPEs), especially in e-waste recycling areas. In this study, we conducted a comprehensive survey to monitor a broad suite of 11 traditional tri-OPEs, 12 emerging OPEs, and 10 di-OPEs in indoor dust collected from the workshops of (n = 42) and residential homes adjacent to (n = 24) a mega e-waste recycling industrial park in South China. In addition to traditional tri-OPEs, all of the emerging OPEs and di-OPEs were frequently detected in the dust samples. Total concentrations of emerging tri-OPEs and di-OPEs were in the range of 1210-62 900 and 2010-55 600 ng/g in the workshop dust and 435-23 700 and 186-4350 ng/g in the local home dust, respectively, which were comparable to those of traditional tri-OPEs (1160-61 500 and 370- 13 900 ng/g, respectively). Most OPEs exhibited significantly higher concentrations in workshop dust versus local home dust (p < 0.05), indicating that e-waste dismantling activities contributed to the high residues of OPEs in indoor dust. Correlation analysis revealed that tri-OPEs have some common emission sources, i.e., e-waste and household products, while di-OPEs could originate from different sources, e.g., tri-OPE degradation, direct commercial application, and impurities in tri-OPE formulas. For both occupational workers and local adults, the median estimated daily intake values of emerging tri-OPEs (7.5 and 1.7 ng/kg bw/day, respectively) and di-OPEs (3.9 and 0.2 ng/kg bw/day, respectively) were comparable to that of traditional tri-OPEs (4.3 and 1.0 ng/ kg bw/day, respectively), which suggests the important contribution of the emerging tri-OPEs and di-OPEs to the overall risks of human external exposure to OPE chemicals.
机译:许多研究报告了传统的有机磷酸酯的环境污染(三相),但是关于新出现的三种作品和有机磷酸二酯(二官能)的信息很少,特别是在电子废物回收区域中。在这项研究中,我们进行了全面的调查,以监测11个传统三款的广泛套件,12个新兴运行,以及从(n = 42)和邻近的住宅的室内灰尘中的10个Di-opes(n = 24)南方的Mega E废废回收工业园。除了传统的三作品外,在粉尘样品中经常检测到所有新出现的OPE和Di-opes。在当地家庭灰尘中,新兴三件和二作用的总浓度为1210-62 900和2010-55600和2010 - 55 600 Ng / g,435-23 700和186-4350 Ng / g,分别与传统三件(1160-61 500和370-13 900ng / g)相当的比较。大多数款项在车间尘埃中显示出显着更高的浓度与当地家庭灰尘(P <0.05),表明电子废物拆解活动导致室内粉尘中的效果高残留。相关性分析显示,三相作用具有一些常见的发射源,即电子废物和家用产品,而二官部可以源自不同来源,例如三-Ope降解,直接商业应用和三欧式公式中的杂质。对于职业工人和当地成年人来说,新兴三件(分别为7.5和1.7ng / kg Bw / day)和二作用(分别为3.9和0.2ng / kg /天)的中位数估计的每日摄入量与传统三项款项(分别为4.3和1.0ng / kg / kg /天)相当,这表明了新兴三件的重要贡献和Di-opps对ope化学品的人体外部暴露的总体风险。

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  • 来源
    《Environmental Science & Technology》 |2020年第19期|12001-12012|共12页
  • 作者单位

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

    Guangdong Key Laboratory of Environmental Pollution and Health School of Environment Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality Jinan University Guangzhou 511443 China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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