...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Environmental Science & Technology >Delineating Oxidative Processes Of Aqueous C_(60) Preparations: Role Of Thf Peroxide
【24h】

Delineating Oxidative Processes Of Aqueous C_(60) Preparations: Role Of Thf Peroxide

机译：描绘C_（60）水溶液的氧化过程：过氧化物的作用

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The oxidative reactivity of THF derivatives formed during THFC_(60) synthesis was evaluated with indigo dye as a model compound. The results showed that the formation of previously undetected oxidizing agents during THFC_(60), synthesis accounted for the degradation of indigo dye by THFC_(60) (THFC_(60)/unwashed), while THFC_(60) after vigorous washing (THFC_(60)/washed) and nC_(60) prepared without the use of THF were not reactive. γ-Butyrolactone (GBL) was detected by GC-MS in the THFC_(60)/unwashed as one of THF derivatives, but showed no reactivity with indigo dye. An organic peroxide was detected in the THFC_(60)/unwashed by HPLC,and was reactive with indigo dye. This compound was found to also account for the elevated antibacterial and bactericidal activities of THF/ nC-(60)/unwashed on E, coli. Analysis by LC/(+ESI)MS and ~1H NMR showed that the detected THF peroxide was tetrahydro-2-(tetrahydrofuran-2-ylperoxy)furan, The formation of THF peroxide during the preparation of aqueous stable C_(60) aggregates provides another potential explanation for the reactivity and oxidative stress mechanisms of THFC-(60) system reported in the literature, although it does not exclude the potential reactivity and toxicity of nC_(60) itself.
机译：以靛蓝染料为模型化合物评价了在THF / nC_（60）合成过程中形成的THF衍生物的氧化反应性。结果表明，在THF / nC_（60）过程中形成了以前未发现的氧化剂，合成解释了靛蓝染料被THF / nC_（60）（THF / nC_（60）/未洗涤）降解的原因，而THF / nC_（剧烈洗涤后（60℃）（THF / nC_（60）/洗涤）和不使用THF制备的nC_（60）不反应。通过GC-MS在THF / nC_（60）/未洗涤中作为THF衍生物之一检测到γ-丁内酯（GBL），但与靛蓝染料无反应性。在THF / nC_（60）中检测到有机过氧化物，未经HPLC洗涤，该有机过氧化物可与靛蓝染料反应。发现该化合物还解释了THF / nC-（60）/未在大肠杆菌上洗涤的增强的抗菌和杀菌活性。 LC /（+ ESI）MS和〜1H NMR分析表明，检测到的THF过氧化物为四氢-2-（四氢呋喃-2-基过氧）呋喃，在制备稳定的C_（60）水性聚集体过程中形成了THF过氧化物。尽管没有排除nC_（60）本身的潜在反应性和毒性，但文献中报道了THF / nC-（60）系统的反应性和氧化应激机制的另一种潜在解释。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号