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Assessment of Exposure of Workers and Swimmers to Trihalomethanes in an Indoor Swimming Pool

机译:室内游泳池中工人和游泳者暴露于三卤甲烷的评估

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摘要

A simultaneous study on workers' and swimmers' exposure to trihalomethanes (THMs) in an indoor swimming pool has been carried out by analyzing urine samples using the headspace and gas chromatography-mass spectrometry technique. The subjects of this study were male and female workers of an indoor swimming pool as well as swimmers regularly attending the pool. The results reported show that only chloroform and bromodichloromethane were detected in the urine of those people exposed, which can be used as a specific index of exposure to these compounds. THM uptake of swimmers after 1 h of swimming was higher than that of workers after a 4 h work shift since THM levels in the workers' urine were associated only with inhalation, while levels in swimmers' urine were mainly associated with dermal absorption, apart from inhalation and occasional ingestion, as well as increased uptake due to the physical stress (swimming). The kinetics of THM excretion in the urine of the participants exposed has been calculated aftertermination of the exposure to select the sampling time and determine the elimination process. An interval of 15 min after exposure was selected as the sampling time, and the absorbed dosage was eliminated by 2 h after exposure. A good correlation between THM concentrations found in the swimming pool water and the urinary THM concentrations of the people affected after exposure has also been obtained.
机译:通过使用顶空和气相色谱-质谱技术分析尿液样本,对工人和游泳者在室内游泳池中暴露于三卤甲烷(THMs)的同时进行了研究。这项研究的对象是室内游泳池的男性和女性工人,以及定期参加游泳池的游泳者。报告的结果表明,在这些接触者的尿液中仅检测到氯仿和溴代二氯甲烷,可以用作这些化合物接触的特定指标。游泳1小时后,游泳者的THM摄取量高于工作4小时后,工人的THM摄取量,因为工人尿液中THM的含量仅与吸入有关,而游泳者尿液中的THM含量主要与皮肤吸收有关。吸入和不定期摄入,以及由于身体压力(游泳)而导致摄入量增加。终止接触后,要计算出接触参与者尿液中THM的排泄动力学,以选择采样时间并确定消除过程。选择暴露后15分钟的间隔作为采样时间,并在暴露后2 h消除吸收剂量。还获得了游泳池水中发现的THM浓度与接触后受影响人群的尿THM浓度之间的良好相关性。

著录项

  • 来源
    《Environmental Science & Technology》 |2007年第13期|p.4793-4798|共6页
  • 作者

    J. CARO; M. GALLEGO;

  • 作者单位

    Department of Analytical Chemistry, Campus of Rabanales, University of Cordoba, E-14071 Cordoba, Spain;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 环境化学;
  • 关键词

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