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首页> 外文期刊>Environmental Science & Technology >Levels of the Flame Retardants Hexabromocyclododecane and Tetrabromobisphenol A in the Blubber of Harbor Porpoises (Phocoena phocoena) Stranded or Bycaught in the U.K.,with Evidence for an Increase in HBCD Concentrations in Recent Years
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Levels of the Flame Retardants Hexabromocyclododecane and Tetrabromobisphenol A in the Blubber of Harbor Porpoises (Phocoena phocoena) Stranded or Bycaught in the U.K.,with Evidence for an Increase in HBCD Concentrations in Recent Years

机译：在英国被搁浅或捕获的海港海豚（Phocoena phocoena）的硬脂中六溴环十二烷和四溴双酚A的阻燃剂水平，最近几年的HBCD浓度有所增加的证据

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Within the U.K.Marine Mammals Stranding Program,analysis of brominated flame retardants began in 1999.Initially,the focus of attention was the brominated diphenyl ethers.Since the withdrawal of the pentamix and octamix polybrominated diphenyl ether (PBDE) formulations from the EU market prior to August 2004,two other high-volume products,hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBP-A),have been included.We report the concentrations of these compounds in the blubber of harbor porpoises (Phocoena phocoena) stranded or dying due to physical trauma in the U.K.during the period 1994-2003.Analysis was undertaken using LC/MS method on a diastereoisomer basis.Eighty-five samples were analyzed for HBCD,and 68 of these for TBBP-A.a-HBCD dominated over the other isomers and was detected in all samples analyzed at concentrations ranging from 10 to 19 200 mu g kg~(-1) wet weight.The maximum concentration was about double that reported in earlier U.K.studies.TBBP-A was detected in only 18 samples and at much lower concentrations,from 6 to 35 mu g kg~(-1) wet weight.Investigation of possible time trends indicated a sharp increase in HBCD concentrations from about 2001 onward,which was not confounded by age (length),sex,nutritional status,or location.This may be a result of changing patterns of use of HBCD following limitations on the production and use of two PBDE formulations within the EU and will feed ongoing risk assessment activities.
机译：在英国海洋哺乳动物链计划中，溴化阻燃剂的分析始于1999年。最初，关注的焦点是溴化二苯醚。由于五甲基苯甲醚和八胺多溴联苯二苯醚（PBDE）制剂在欧盟市场退出之前， 2004年8月，还包括了另外两种高容量产品，六溴环十二烷（HBCD）和四溴双酚A（TBBP-A）。我们报告了由于物理原因而搁浅或垂死的海豚海豚（Phocoena phocoena）的脂中这些化合物的浓度。在1994年至2003年期间，英国采用非对映异构体方法进行了分析。分析了85个样品中的HBCD，其中68个样品中的TBBP-Aa-HBCD高于其他异构体。在所有分析样品中检测到的湿重为10至19200μg kg〜（-1）的样品中，最大浓度约为早期UK研究报告的两倍。仅18个样品，且浓度很低，从6到35μg kg〜（-1）湿重。对可能的时间趋势的研究表明，从2001年左右开始，六溴环十二烷的浓度急剧增加，这不受年龄（长度）的影响。 ，性别，营养状况或位置。这可能是由于在欧盟范围内限制生产和使用两种多溴二苯醚制剂而改变了六溴环十二烷的使用方式，并将为正在进行的风险评估活动提供依据。

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  • 来源
    《Environmental Science & Technology》 |2006年第7期|p.2177-2183|共7页
  • 作者

    ROBIN J.LAW; PHILIPPE BERSUDER; COLIN R.ALLCHIN; JON BARRY;

  • 作者单位

    The Centre for Environment,Fisheries and Aquaculture Science,CEFAS Burnham Laboratory,Remembrance Avenue,Burnham on Crouch,Essex CM0 8HA,U.K.;

    The Centre for Environment,Fisheries and Aquaculture Science,CEFAS Burnham Laboratory,Remembrance Avenue,Burnham on Crouch,Essex CM0 8HA,U.K.;

    The Centre for Environment,Fisheries and Aquaculture Science,CEFAS Burnham Laboratory,Remembrance Avenue,Burnham on Crouch,Essex CM0 8HA,U.K.;

    The Centre for Environment,Fisheries and Aquaculture Science,CEFAS Burnham Laboratory,Remembrance Avenue,Burnham on Crouch,Essex CM0 8HA,U.K.;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
  • 中图分类 环境化学;
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